Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

Baishu Zheng; Junfeng Bai; Jingui Duan; Lukasz Wojtas; Michael J. Zaworotko

doi:10.1021/ja110042b

Enhanced CO₂ binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

Baishu Zheng, Junfeng Bai, Jingui Duan, Lukasz Wojtas, Michael J. Zaworotko

科研成果: 期刊稿件 › 文章 › 同行评审

721 引用（Scopus）

摘要

An rht-type metal-organic framework (MOF) prepared from M ₂(carboxylate)₄ (M = Cu, Co) paddlewheel clusters and a flexible C₃-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO₂ uptake, an enhanced heat of adsorption, and higher selectivity toward CO₂/N₂ in comparison with what was previously observed for an analogous MOF with alkyne groups.

源语言	英语
页（从-至）	748-751
页数	4
期刊	Journal of the American Chemical Society
卷	133
期	4
DOI	https://doi.org/10.1021/ja110042b
出版状态	已出版 - 2 2月 2011
已对外发布	是

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10.1021/ja110042b

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abstract = "An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.",

author = "Baishu Zheng and Junfeng Bai and Jingui Duan and Lukasz Wojtas and Zaworotko, {Michael J.}",

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AU - Zheng, Baishu

AU - Bai, Junfeng

AU - Duan, Jingui

AU - Wojtas, Lukasz

AU - Zaworotko, Michael J.

PY - 2011/2/2

Y1 - 2011/2/2

N2 - An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.

AB - An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.

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ER -

Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

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Enhanced CO₂ binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups