Epoxidation of soybean oil by continuous micro-flow system with continuous separation

Wei He; Zheng Fang; Dong Ji; Ketao Chen; Zhidong Wan; Xin Li; Haifeng Gan; Shigui Tang; Kai Zhang; Kai Guo

doi:10.1021/op400050n

Epoxidation of soybean oil by continuous micro-flow system with continuous separation

Wei He, Zheng Fang, Dong Ji, Ketao Chen, Zhidong Wan, Xin Li, Haifeng Gan, Shigui Tang, Kai Zhang, Kai Guo

生物与制药工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

58 引用（Scopus）

摘要

In the study, the epoxidation process of soybean oil by microflow system (MFS) was investigated. With formic acid as oxygen carrier and EDTA-2Na as stabilizer, the optimal result (epoxidized soybean oil (ESO) with an epoxy number (EN) of 7.3) was obtained in such conditions: temperature 75 C, H ₂SO₄ concentration 3%, EDTA-2Na dosage 3%, residence time 6.7 min, ratio of formic acid to hydrogen peroxide 1:1, and H₂O ₂ to double bond molar ratio 8:1.

源语言	英语
页（从-至）	1137-1141
页数	5
期刊	Organic Process Research and Development
卷	17
期	9
DOI	https://doi.org/10.1021/op400050n
出版状态	已出版 - 20 9月 2013

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abstract = "In the study, the epoxidation process of soybean oil by microflow system (MFS) was investigated. With formic acid as oxygen carrier and EDTA-2Na as stabilizer, the optimal result (epoxidized soybean oil (ESO) with an epoxy number (EN) of 7.3) was obtained in such conditions: temperature 75 C, H 2SO4 concentration 3%, EDTA-2Na dosage 3%, residence time 6.7 min, ratio of formic acid to hydrogen peroxide 1:1, and H2O 2 to double bond molar ratio 8:1.",

author = "Wei He and Zheng Fang and Dong Ji and Ketao Chen and Zhidong Wan and Xin Li and Haifeng Gan and Shigui Tang and Kai Zhang and Kai Guo",

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doi = "10.1021/op400050n",

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AU - He, Wei

AU - Fang, Zheng

AU - Ji, Dong

AU - Chen, Ketao

AU - Wan, Zhidong

AU - Li, Xin

AU - Gan, Haifeng

AU - Tang, Shigui

AU - Zhang, Kai

AU - Guo, Kai

PY - 2013/9/20

Y1 - 2013/9/20

N2 - In the study, the epoxidation process of soybean oil by microflow system (MFS) was investigated. With formic acid as oxygen carrier and EDTA-2Na as stabilizer, the optimal result (epoxidized soybean oil (ESO) with an epoxy number (EN) of 7.3) was obtained in such conditions: temperature 75 C, H 2SO4 concentration 3%, EDTA-2Na dosage 3%, residence time 6.7 min, ratio of formic acid to hydrogen peroxide 1:1, and H2O 2 to double bond molar ratio 8:1.

AB - In the study, the epoxidation process of soybean oil by microflow system (MFS) was investigated. With formic acid as oxygen carrier and EDTA-2Na as stabilizer, the optimal result (epoxidized soybean oil (ESO) with an epoxy number (EN) of 7.3) was obtained in such conditions: temperature 75 C, H 2SO4 concentration 3%, EDTA-2Na dosage 3%, residence time 6.7 min, ratio of formic acid to hydrogen peroxide 1:1, and H2O 2 to double bond molar ratio 8:1.

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SN - 1083-6160

VL - 17

SP - 1137

EP - 1141

JO - Organic Process Research and Development

JF - Organic Process Research and Development

IS - 9

ER -

Epoxidation of soybean oil by continuous micro-flow system with continuous separation

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