Fe/Fe3C/N-Doped Carbon Materials from Metal–Organic Framework Composites as Highly Efficient Oxygen Reduction Reaction Electrocatalysts

Yuhong Qian, Jack Cavanaugh, Inayat Ali Khan, Xuerui Wang, Yongwu Peng, Zhigang Hu, Yuxiang Wang, Dan Zhao

科研成果: 期刊稿件文章同行评审

31 引用 (Scopus)

摘要

A series of Fe/Fe3C-containing N-doped porous carbon materials (Fe/NC) were prepared by pyrolyzing composites that contained a metal–organic framework (MIL-88c-Fe) with dicyandiamide. The Fe/NC obtained at 800 °C (Fe/NC800) showed comparable onset potential and kinetics to that of the commercial Pt/C catalyst in catalyzing the oxygen reduction reaction (ORR). Further measurements suggested that it has better durability and much higher methanol tolerance than Pt/C. Acid leaching was performed to reveal the critical role of Fe-containing sites in ORR catalysis.

源语言英语
页(从-至)718-723
页数6
期刊ChemPlusChem
81
8
DOI
出版状态已出版 - 1 8月 2016
已对外发布

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