Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant

Hai Huang, Luning Tang, Qi Liu, Yang Xi, Guangke He, Hongjun Zhu

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19 引用 (Scopus)

摘要

A novel chalcogen-mediated oxyfunctionalization mode of ynamides for the synthesis of α-chalcogenyl acrylamides has been developed. Independent of metal catalysts, external oxidants and additives, this mild process afforded a range of structurally diverse α-chalcogenyl acrylamides, including α-selanyl acrylamides and α-tellanyl acrylamides. Interestingly, diverse ynamides tolerated in this approach gave different stereoselectivities.

源语言英语
页(从-至)5605-5608
页数4
期刊Chemical Communications
52
32
DOI
出版状态已出版 - 25 4月 2016

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