Fusing high symmetric coordination polyhedrons of Cu6(PIP) 4, Cu12(PIP)8, and Cu12(PIP) 24 into an unprecedented porous MOF: Synthesis, structure, and its remarkable CO2 selectivity

Ruirui Yun, Jingui Duan, Junfeng Bai, Yizhi Li

科研成果: 期刊稿件文章同行评审

30 引用 (Scopus)

摘要

An unprecedented metal-organic framework, NJU-Bai6, formed by piling up the nanocages Cu6(PIP)4, Cu12(PIP)8, and Cu12(PIP)24 through sharing faces of the "opened" triangular and square windows, has been designed and structurally characterized. Very interestingly, it exhibits the third highest selectivity of CO2 over N2 with the value about 60 at room temperature.

源语言英语
页(从-至)24-26
页数3
期刊Crystal Growth and Design
13
1
DOI
出版状态已出版 - 2 1月 2013
已对外发布

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