[Ga@Bi10(NbMes)2]3−: a linear Nb-GaI-Nb filament coordinated by a bismuth cage

Lei Qiao; Tao Yang; Gernot Frenking; Zhong Ming Sun

doi:10.1039/d3cc00631j

[Ga@Bi₁₀(NbMes)₂]³⁻: a linear Nb-Ga^I-Nb filament coordinated by a bismuth cage

Lei Qiao, Tao Yang, Gernot Frenking, Zhong Ming Sun

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

In this work, we report a low-valent Ga(i) complex, [Ga@Bi₁₀(NbMes)₂]³⁻, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

源语言	英语
页（从-至）	4024-4027
页数	4
期刊	Chemical Communications
卷	59
期	27
DOI	https://doi.org/10.1039/d3cc00631j
出版状态	已出版 - 8 3月 2023
已对外发布	是

访问文件

10.1039/d3cc00631j

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{af4faaa19bfe4b87bb59922f35506219,

title = "[Ga@Bi10(NbMes)2]3−: a linear Nb-GaI-Nb filament coordinated by a bismuth cage",

abstract = "In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.",

author = "Lei Qiao and Tao Yang and Gernot Frenking and Sun, {Zhong Ming}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = mar,

day = "8",

doi = "10.1039/d3cc00631j",

language = "英语",

volume = "59",

pages = "4024--4027",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "27",

}

TY - JOUR

T1 - [Ga@Bi10(NbMes)2]3−

T2 - a linear Nb-GaI-Nb filament coordinated by a bismuth cage

AU - Qiao, Lei

AU - Yang, Tao

AU - Frenking, Gernot

AU - Sun, Zhong Ming

PY - 2023/3/8

Y1 - 2023/3/8

N2 - In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

AB - In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

UR - http://www.scopus.com/inward/record.url?scp=85150897718&partnerID=8YFLogxK

U2 - 10.1039/d3cc00631j

DO - 10.1039/d3cc00631j

M3 - 文章

C2 - 36920786

AN - SCOPUS:85150897718

SN - 1359-7345

VL - 59

SP - 4024

EP - 4027

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

[Ga@Bi10(NbMes)2]3−: a linear Nb-GaI-Nb filament coordinated by a bismuth cage

摘要

访问文件

其它文件与链接

指纹

引用此

[Ga@Bi₁₀(NbMes)₂]³⁻: a linear Nb-Ga^I-Nb filament coordinated by a bismuth cage