Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates

Magesh Sampath; Teck Peng Loh

doi:10.1039/c0sc00123f

Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates

Magesh Sampath, Teck Peng Loh

Nanyang Technological University

科研成果: 期刊稿件 › 文章 › 同行评审

124 引用（Scopus）

摘要

Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes with both good yields and excellent selectivities of up to 99%.

源语言	英语
页（从-至）	739-742
页数	4
期刊	Chemical Science
卷	1
期	6
DOI	https://doi.org/10.1039/c0sc00123f
出版状态	已出版 - 1 12月 2010
已对外发布	是

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title = "Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates",

abstract = "Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes with both good yields and excellent selectivities of up to 99%.",

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N2 - Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes with both good yields and excellent selectivities of up to 99%.

AB - Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes with both good yields and excellent selectivities of up to 99%.

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Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates

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