Highly enantioselective and anti -diastereoselective catalytic intermolecular glyoxylate-ene reactions: Effect of the geometrical isomers of alkenes

Xiang Zhang, Min Wang, Ran Ding, Yun He Xu, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

14 引用 (Scopus)

摘要

An efficient method for the synthesis of homoallylic alcohols with high enantioselectivities and anti-diastereoselectivities via an In(III)-catalyzed intermolecular glyoxylate-ene reaction has been developed. The geometrical isomers of alkenes were shown to have different reactivities. Only the isomers of the alkenes having a proton β-cis to the substituent reacted in this catalytic system.

源语言英语
页(从-至)2736-2739
页数4
期刊Organic Letters
17
11
DOI
出版状态已出版 - 5 6月 2015
已对外发布

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