Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

Jun Feng Zhao; Hoi Yan Tsui; Pei Jia Wu; Jun Lu; Teck Peng Loh

doi:10.1021/ja807501a

Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

Jun Feng Zhao, Hoi Yan Tsui, Pei Jia Wu, Jun Lu, Teck Peng Loh

Nanyang Technological University

科研成果: 期刊稿件 › 文章 › 同行评审

65 引用（Scopus）

摘要

A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

源语言	英语
页（从-至）	16492-16493
页数	2
期刊	Journal of the American Chemical Society
卷	130
期	49
DOI	https://doi.org/10.1021/ja807501a
出版状态	已出版 - 10 12月 2008
已对外发布	是

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abstract = "A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.",

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AU - Zhao, Jun Feng

AU - Tsui, Hoi Yan

AU - Wu, Pei Jia

AU - Lu, Jun

AU - Loh, Teck Peng

PY - 2008/12/10

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N2 - A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

AB - A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

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Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

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