Homoallyllic nitrone isomerization: Convenient enantioselective synthesis of homoallylic nitrones and homoallylic hydroxylamines

Hin Soon Cheng; Ai Hua Seow; Teck Peng Loh

doi:10.1021/ol800925v

Homoallyllic nitrone isomerization: Convenient enantioselective synthesis of homoallylic nitrones and homoallylic hydroxylamines

Hin Soon Cheng, Ai Hua Seow, Teck Peng Loh

Nanyang Technological University

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

(Chemical Equation Presented) An α-regioselective synthesis of homoallylic nitrones from aldehydes is reported on the basis of [3,3]-sigmatropic rearrangement. The products are obtained in up to 99% enantioselectivity and up to 80% yield under environmentally benign and mild reaction conditions.

源语言	英语
页（从-至）	2805-2807
页数	3
期刊	Organic Letters
卷	10
期	13
DOI	https://doi.org/10.1021/ol800925v
出版状态	已出版 - 2008
已对外发布	是

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10.1021/ol800925v

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abstract = "(Chemical Equation Presented) An α-regioselective synthesis of homoallylic nitrones from aldehydes is reported on the basis of [3,3]-sigmatropic rearrangement. The products are obtained in up to 99% enantioselectivity and up to 80% yield under environmentally benign and mild reaction conditions.",

author = "Cheng, {Hin Soon} and Seow, {Ai Hua} and Loh, {Teck Peng}",

year = "2008",

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AU - Seow, Ai Hua

AU - Loh, Teck Peng

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) An α-regioselective synthesis of homoallylic nitrones from aldehydes is reported on the basis of [3,3]-sigmatropic rearrangement. The products are obtained in up to 99% enantioselectivity and up to 80% yield under environmentally benign and mild reaction conditions.

AB - (Chemical Equation Presented) An α-regioselective synthesis of homoallylic nitrones from aldehydes is reported on the basis of [3,3]-sigmatropic rearrangement. The products are obtained in up to 99% enantioselectivity and up to 80% yield under environmentally benign and mild reaction conditions.

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U2 - 10.1021/ol800925v

DO - 10.1021/ol800925v

M3 - 文章

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SN - 1523-7060

VL - 10

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Homoallyllic nitrone isomerization: Convenient enantioselective synthesis of homoallylic nitrones and homoallylic hydroxylamines

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