TY - JOUR
T1 - Homogenizing Morphology and Composition of Methylammonium-Free Wide-Bandgap Perovskite for Efficient and Stable Tandem Solar Cells
AU - Lian, Xinxin
AU - Xu, Ye
AU - Fu, Wei
AU - Meng, Rui
AU - Ma, Quanxing
AU - Xu, Chunyu
AU - Luo, Ming
AU - Hu, Ying
AU - Han, Junchao
AU - Min, Hao
AU - Krishna, Anurag
AU - Chen, Yifan
AU - Zhou, Huawei
AU - Zhang, Xueling
AU - Chen, Cong
AU - Chang, Jin
AU - Li, Can
AU - Chen, Yifeng
AU - Feng, Zhiqiang
AU - Li, Zhen
AU - Zuo, Guangzheng
AU - Gao, Jifan
AU - Zhang, Hong
AU - Mo, Xiaoliang
AU - Chu, Junhao
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024/9/11
Y1 - 2024/9/11
N2 - A facile and eco-friendly dimethyl sulfoxide-mediated solution aging (DMSA) treatment is presented to control the crystallization dynamics of methylammonium (MA)-free wide-bandgap (WBG) perovskite films, enhancing film quality, and morphology for high-performance tandem solar cells. The comprehensive structural, morphological, and characterization analyses reveal that the DMSA treatment significantly enhances composition and morphology homogeneity while suppressing halide segregation. Consequently, opaque, and semi-transparent MA-free WBG perovskite solar cells (PSCs) exhibit remarkable power conversion efficiencies (PCEs) of 18.28% and 17.61%, respectively. Notably, the unencapsulated DMSA-treated devices maintain 95% of the initial PCE after 900 h of continuous operation at 55 °C ± 5 °C. Furthermore, stacking semi-transparent DMSA-treated PSCs as top cells in a 4T tandem configuration, along with silicon heterojunction (SHJ), lead–tin (Pb–Sn) alloyed PSCs, and organic photovoltaics (OPV) as bottom cells, yields impressive PCEs of 28.09%, 26.09%, and 25.28%, respectively, for the fabricated tandem cells. This innovative approach opens new avenues for enhancing the photo-stability and photovoltaic performance of perovskite-based tandem solar cells.
AB - A facile and eco-friendly dimethyl sulfoxide-mediated solution aging (DMSA) treatment is presented to control the crystallization dynamics of methylammonium (MA)-free wide-bandgap (WBG) perovskite films, enhancing film quality, and morphology for high-performance tandem solar cells. The comprehensive structural, morphological, and characterization analyses reveal that the DMSA treatment significantly enhances composition and morphology homogeneity while suppressing halide segregation. Consequently, opaque, and semi-transparent MA-free WBG perovskite solar cells (PSCs) exhibit remarkable power conversion efficiencies (PCEs) of 18.28% and 17.61%, respectively. Notably, the unencapsulated DMSA-treated devices maintain 95% of the initial PCE after 900 h of continuous operation at 55 °C ± 5 °C. Furthermore, stacking semi-transparent DMSA-treated PSCs as top cells in a 4T tandem configuration, along with silicon heterojunction (SHJ), lead–tin (Pb–Sn) alloyed PSCs, and organic photovoltaics (OPV) as bottom cells, yields impressive PCEs of 28.09%, 26.09%, and 25.28%, respectively, for the fabricated tandem cells. This innovative approach opens new avenues for enhancing the photo-stability and photovoltaic performance of perovskite-based tandem solar cells.
KW - homogeneity
KW - methylammonium-free
KW - perovskite solar cells
KW - tandem solar cells
KW - wide-bandgap perovskite
UR - http://www.scopus.com/inward/record.url?scp=85190606524&partnerID=8YFLogxK
U2 - 10.1002/adfm.202402061
DO - 10.1002/adfm.202402061
M3 - 文章
AN - SCOPUS:85190606524
SN - 1616-301X
VL - 34
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 37
M1 - 2402061
ER -
