Hydrogen absorption in Ti45 Zr35 Ni17 Cu3 amorphous and quasicrystalline alloy powders

Baozhong Liu; Dongming Liu; Yaoming Wu; Liquan Li; Limin Wang

doi:10.1016/j.ijhydene.2006.11.007

Hydrogen absorption in Ti₄₅ Zr₃₅ Ni₁₇ Cu₃ amorphous and quasicrystalline alloy powders

Baozhong Liu, Dongming Liu, Yaoming Wu, Liquan Li, Limin Wang

材料科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

Ti₄₅ Zr₃₅ Ni₁₇ Cu₃ amorphous and icosahedral quasicrystalline (I-phase) powders were synthesized by mechanical alloying (MA) and subsequent annealing, the phase structure and hydrogen absorption properties of two powders were investigated. XRD analysis indicated that the MAed powder was an amorphous phase and annealed powder was an I-phase. Two alloy exhibited excellent hydrogen adsorption property and started to absorb hydrogen without induction time. PCT measurement showed that the plateau pressure of the amorphous powders was obviously higher than that of the I-phase powders. After the first hydrogen cycling, the partial amorphous phase changed to (Zr, Ti) H₂ phases, and the I-phase was steady. Similar hydride phases Ti₂ ZrH₄ and (Zr, Ti) H₂ were also formed after the second hydrogen cycling for the amorphous and I-phase alloy powders.

源语言	英语
页（从-至）	2429-2433
页数	5
期刊	International Journal of Hydrogen Energy
卷	32
期	13
DOI	https://doi.org/10.1016/j.ijhydene.2006.11.007
出版状态	已出版 - 9月 2007

联合国可持续发展目标

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10.1016/j.ijhydene.2006.11.007

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title = "Hydrogen absorption in Ti45 Zr35 Ni17 Cu3 amorphous and quasicrystalline alloy powders",

abstract = "Ti45 Zr35 Ni17 Cu3 amorphous and icosahedral quasicrystalline (I-phase) powders were synthesized by mechanical alloying (MA) and subsequent annealing, the phase structure and hydrogen absorption properties of two powders were investigated. XRD analysis indicated that the MAed powder was an amorphous phase and annealed powder was an I-phase. Two alloy exhibited excellent hydrogen adsorption property and started to absorb hydrogen without induction time. PCT measurement showed that the plateau pressure of the amorphous powders was obviously higher than that of the I-phase powders. After the first hydrogen cycling, the partial amorphous phase changed to (Zr, Ti) H2 phases, and the I-phase was steady. Similar hydride phases Ti2 ZrH4 and (Zr, Ti) H2 were also formed after the second hydrogen cycling for the amorphous and I-phase alloy powders.",

keywords = "Amorphous phase, Hydrogen adsorption, Icosahedral quasicrystal, Mechanical alloying, Ti-Zr-Ni-Cu alloy",

author = "Baozhong Liu and Dongming Liu and Yaoming Wu and Liquan Li and Limin Wang",

year = "2007",

month = sep,

doi = "10.1016/j.ijhydene.2006.11.007",

language = "英语",

volume = "32",

pages = "2429--2433",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "13",

}

TY - JOUR

T1 - Hydrogen absorption in Ti45 Zr35 Ni17 Cu3 amorphous and quasicrystalline alloy powders

AU - Liu, Baozhong

AU - Liu, Dongming

AU - Wu, Yaoming

AU - Li, Liquan

AU - Wang, Limin

PY - 2007/9

Y1 - 2007/9

N2 - Ti45 Zr35 Ni17 Cu3 amorphous and icosahedral quasicrystalline (I-phase) powders were synthesized by mechanical alloying (MA) and subsequent annealing, the phase structure and hydrogen absorption properties of two powders were investigated. XRD analysis indicated that the MAed powder was an amorphous phase and annealed powder was an I-phase. Two alloy exhibited excellent hydrogen adsorption property and started to absorb hydrogen without induction time. PCT measurement showed that the plateau pressure of the amorphous powders was obviously higher than that of the I-phase powders. After the first hydrogen cycling, the partial amorphous phase changed to (Zr, Ti) H2 phases, and the I-phase was steady. Similar hydride phases Ti2 ZrH4 and (Zr, Ti) H2 were also formed after the second hydrogen cycling for the amorphous and I-phase alloy powders.

AB - Ti45 Zr35 Ni17 Cu3 amorphous and icosahedral quasicrystalline (I-phase) powders were synthesized by mechanical alloying (MA) and subsequent annealing, the phase structure and hydrogen absorption properties of two powders were investigated. XRD analysis indicated that the MAed powder was an amorphous phase and annealed powder was an I-phase. Two alloy exhibited excellent hydrogen adsorption property and started to absorb hydrogen without induction time. PCT measurement showed that the plateau pressure of the amorphous powders was obviously higher than that of the I-phase powders. After the first hydrogen cycling, the partial amorphous phase changed to (Zr, Ti) H2 phases, and the I-phase was steady. Similar hydride phases Ti2 ZrH4 and (Zr, Ti) H2 were also formed after the second hydrogen cycling for the amorphous and I-phase alloy powders.

KW - Amorphous phase

KW - Hydrogen adsorption

KW - Icosahedral quasicrystal

KW - Mechanical alloying

KW - Ti-Zr-Ni-Cu alloy

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U2 - 10.1016/j.ijhydene.2006.11.007

DO - 10.1016/j.ijhydene.2006.11.007

M3 - 文章

AN - SCOPUS:34548135212

SN - 0360-3199

VL - 32

SP - 2429

EP - 2433

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 13

ER -

Hydrogen absorption in Ti45 Zr35 Ni17 Cu3 amorphous and quasicrystalline alloy powders

摘要

联合国可持续发展目标

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引用此

Hydrogen absorption in Ti₄₅ Zr₃₅ Ni₁₇ Cu₃ amorphous and quasicrystalline alloy powders