TY - JOUR
T1 - Hydrothermal Synthesis, Crystal Structure and Properties of a New Porous Zinc Arsenite Zn3As2O6 with the Novel Helical Zn-O Chains
AU - Meng, Lianxia
AU - Zhou, Guangpeng
AU - Zhu, Dunru
AU - Xu, Yan
PY - 2009/12
Y1 - 2009/12
N2 - A new porous zinc arsenite Zn3As2O6 1 has been synthesized under hydrothermal conditions, and characterized by X-ray single crystal diffraction, IR and TG analysis. The structural analysis reveals that compound 1 is constructed from a network of AsO3 trigonal pyramids and ZnO4 tetrahedra, and represents a 3D framework with one-dimensional 8-membered-ring channels and interesting helical Zn-O chains. Crystal data for 1: Monoclinic, space group P2(1)/c, a = 8. 250(4) Å, b = 5. 186(3) Å, c = 15. 824(9) Å, β = 97. 379(9)°, V = 671. 4(6) Å3, Z = 4, R1 = 0. 0481, and wR2 = 0. 0834.
AB - A new porous zinc arsenite Zn3As2O6 1 has been synthesized under hydrothermal conditions, and characterized by X-ray single crystal diffraction, IR and TG analysis. The structural analysis reveals that compound 1 is constructed from a network of AsO3 trigonal pyramids and ZnO4 tetrahedra, and represents a 3D framework with one-dimensional 8-membered-ring channels and interesting helical Zn-O chains. Crystal data for 1: Monoclinic, space group P2(1)/c, a = 8. 250(4) Å, b = 5. 186(3) Å, c = 15. 824(9) Å, β = 97. 379(9)°, V = 671. 4(6) Å3, Z = 4, R1 = 0. 0481, and wR2 = 0. 0834.
KW - Helical Zn-O chains
KW - Open-framework
KW - Porous
KW - Zinc arsenite
UR - http://www.scopus.com/inward/record.url?scp=72249120421&partnerID=8YFLogxK
U2 - 10.1007/s10876-009-0268-z
DO - 10.1007/s10876-009-0268-z
M3 - 文章
AN - SCOPUS:72249120421
SN - 1040-7278
VL - 20
SP - 651
EP - 660
JO - Journal of Cluster Science
JF - Journal of Cluster Science
IS - 4
ER -