Hydroxylation of Aryl Sulfonium Salts for Phenol Synthesis under Mild Reaction Conditions

Xuan Bo Hu, Qian Qian Fu, Xue Ying Huang, Xue Qiang Chu, Zhi Liang Shen, Chengping Miao, Weiyi Chen

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14 引用 (Scopus)

摘要

Hydroxylation of aryl sulfonium salts could be realized by utilizing acetohydroxamic acid and oxime as hydroxylative agents in the presence of cesium carbonate as a base, leading to a variety of structurally diverse hydroxylated arenes in 47–95% yields. In addition, the reaction exhibited broad functionality tolerance, and a range of important functional groups (e.g., cyano, nitro, sulfonyl, formyl, keto, and ester) could be well amenable to the mild reaction conditions.

源语言英语
文章编号831
期刊Molecules
29
4
DOI
出版状态已出版 - 2月 2024

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