Hypoiodite-mediated metal-free catalytic aziridination of alkenes

Akira Yoshimura; Kyle R. Middleton; Chenjie Zhu; Victor N. Nemykin; Viktor V. Zhdankin

doi:10.1002/anie.201203925

Hypoiodite-mediated metal-free catalytic aziridination of alkenes

Akira Yoshimura, Kyle R. Middleton, Chenjie Zhu, Victor N. Nemykin, Viktor V. Zhdankin

科研成果: 期刊稿件 › 文章 › 同行评审

68 引用（Scopus）

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Look, no metal: A metal-free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m-chloroperoxybenzoic acid (mCPBA) as the terminal oxidant, and N-aminophthalimide as the nitrenium precursor has been developed (see scheme; right: X-ray structure of one of the products). Control experiments suggests that the active oxidant is in situ generated hypoiodous acid (HIO).

源语言	英语
页（从-至）	8059-8062
页数	4
期刊	Angewandte Chemie - International Edition
卷	51
期	32
DOI	https://doi.org/10.1002/anie.201203925
出版状态	已出版 - 6 8月 2012
已对外发布	是

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abstract = "Look, no metal: A metal-free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m-chloroperoxybenzoic acid (mCPBA) as the terminal oxidant, and N-aminophthalimide as the nitrenium precursor has been developed (see scheme; right: X-ray structure of one of the products). Control experiments suggests that the active oxidant is in situ generated hypoiodous acid (HIO).",

keywords = "aziridination, hypoiodous acid, iodine, organocatalysis, oxidation",

author = "Akira Yoshimura and Middleton, {Kyle R.} and Chenjie Zhu and Nemykin, {Victor N.} and Zhdankin, {Viktor V.}",

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AU - Yoshimura, Akira

AU - Middleton, Kyle R.

AU - Zhu, Chenjie

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2012/8/6

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N2 - Look, no metal: A metal-free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m-chloroperoxybenzoic acid (mCPBA) as the terminal oxidant, and N-aminophthalimide as the nitrenium precursor has been developed (see scheme; right: X-ray structure of one of the products). Control experiments suggests that the active oxidant is in situ generated hypoiodous acid (HIO).

AB - Look, no metal: A metal-free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m-chloroperoxybenzoic acid (mCPBA) as the terminal oxidant, and N-aminophthalimide as the nitrenium precursor has been developed (see scheme; right: X-ray structure of one of the products). Control experiments suggests that the active oxidant is in situ generated hypoiodous acid (HIO).

KW - aziridination

KW - hypoiodous acid

KW - iodine

KW - organocatalysis

KW - oxidation

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Hypoiodite-mediated metal-free catalytic aziridination of alkenes

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