In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks

Yi Liu, Melvin Jun Wei Tan, Fengxia Wei, Yufeng Tian, Tom Wu, Christian Kloc, Fengwei Huo, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang

科研成果: 期刊稿件文章同行评审

19 引用 (Scopus)

摘要

Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.

源语言英语
页(从-至)75-78
页数4
期刊CrystEngComm
14
1
DOI
出版状态已出版 - 7 1月 2012
已对外发布

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