Indium-Mediated Reaction of Trialkylsilyl Propargyl Bromide with Aldehydes: Highly Regioselective Synthesis of Allenic and Homopropargylic Alcohols

Man Jing Lin; Teck Peng Loh

doi:10.1021/ja037410i

Indium-Mediated Reaction of Trialkylsilyl Propargyl Bromide with Aldehydes: Highly Regioselective Synthesis of Allenic and Homopropargylic Alcohols

Man Jing Lin, Teck Peng Loh

National University of Singapore

科研成果: 期刊稿件 › 文章 › 同行评审

98 引用（Scopus）

摘要

High regioselective preparation of either the allenic alcohols or homopropargylic alcohols using the indium-mediated reaction of trialkylsilyl propargyl bromides with various aldehydes has been accomplished. By just changing the silyl groups and the reaction conditions, both the allenic and homopropargylic alcohols can be obtained in high regioselectivities.

源语言	英语
页（从-至）	13042-13043
页数	2
期刊	Journal of the American Chemical Society
卷	125
期	43
DOI	https://doi.org/10.1021/ja037410i
出版状态	已出版 - 29 10月 2003
已对外发布	是

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Indium-Mediated Reaction of Trialkylsilyl Propargyl Bromide with Aldehydes: Highly Regioselective Synthesis of Allenic and Homopropargylic Alcohols

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