Indium(III)-Catalyzed Hydration and Hydroalkoxylation of α,β-Unsaturated Ketones in Aqueous Media

Jin Jin Yun, Man Ling Zhi, Wen Xiao Shi, Xue Qiang Chu, Zhi Liang Shen, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

28 引用 (Scopus)

摘要

The hydration of α,β-unsaturated ketones with water proceeded efficiently in the presence of In(OTf)3 (20 mol%) in aqueous media to afford synthetically versatile β-hydroxyketones in moderate to good yields with good functional group compatibility. The method also can be extended to the hydroalkoxylation of α,β-unsaturated ketones with various alcohols for the efficient synthesis of β-alkoxyketones as well as tetrahydrofuran derivatives. (Figure presented.).

源语言英语
页(从-至)2632-2637
页数6
期刊Advanced Synthesis and Catalysis
360
14
DOI
出版状态已出版 - 16 7月 2018

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