Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid

Zhuxiu Zhang; Mengnan Hu; Qiumin Mei; Jihai Tang; Zhaoyang Fei; Xian Chen; Qing Liu; Mifen Cui; Xu Qiao

doi:10.1007/s10934-018-0645-9

Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid

Zhuxiu Zhang, Mengnan Hu, Qiumin Mei, Jihai Tang, Zhaoyang Fei, Xian Chen, Qing Liu, Mifen Cui, Xu Qiao

化工学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Iron-doped mesoporous silica, Fe-MCM-41, with different concentrations of Lewis acidity have been prepared by the hydrothermal method. Physicochemical properties of all Fe-MCM-41 samples were obtained via HRTEM, PXRD and N ₂ sorption characterization. The surface acidities were tested by NH ₃ -TPD. The catalytic activity of all Fe-MCM-41 materials were evaluated in the acidolysis reaction of benzyl chloride with various fatty acids. The corresponding benzaldehyde and acyl chloride product were synthesized in good conversion and high atom efficiency over the catalyst with the highest Fe content.

源语言	英语
页（从-至）	261-269
页数	9
期刊	Journal of Porous Materials
卷	26
期	1
DOI	https://doi.org/10.1007/s10934-018-0645-9
出版状态	已出版 - 15 2月 2019

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title = "Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid",

abstract = " Iron-doped mesoporous silica, Fe-MCM-41, with different concentrations of Lewis acidity have been prepared by the hydrothermal method. Physicochemical properties of all Fe-MCM-41 samples were obtained via HRTEM, PXRD and N 2 sorption characterization. The surface acidities were tested by NH 3 -TPD. The catalytic activity of all Fe-MCM-41 materials were evaluated in the acidolysis reaction of benzyl chloride with various fatty acids. The corresponding benzaldehyde and acyl chloride product were synthesized in good conversion and high atom efficiency over the catalyst with the highest Fe content.",

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author = "Zhuxiu Zhang and Mengnan Hu and Qiumin Mei and Jihai Tang and Zhaoyang Fei and Xian Chen and Qing Liu and Mifen Cui and Xu Qiao",

note = "Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",

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doi = "10.1007/s10934-018-0645-9",

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T1 - Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid

AU - Zhang, Zhuxiu

AU - Hu, Mengnan

AU - Mei, Qiumin

AU - Tang, Jihai

AU - Fei, Zhaoyang

AU - Chen, Xian

AU - Liu, Qing

AU - Cui, Mifen

AU - Qiao, Xu

PY - 2019/2/15

Y1 - 2019/2/15

N2 - Iron-doped mesoporous silica, Fe-MCM-41, with different concentrations of Lewis acidity have been prepared by the hydrothermal method. Physicochemical properties of all Fe-MCM-41 samples were obtained via HRTEM, PXRD and N 2 sorption characterization. The surface acidities were tested by NH 3 -TPD. The catalytic activity of all Fe-MCM-41 materials were evaluated in the acidolysis reaction of benzyl chloride with various fatty acids. The corresponding benzaldehyde and acyl chloride product were synthesized in good conversion and high atom efficiency over the catalyst with the highest Fe content.

AB - Iron-doped mesoporous silica, Fe-MCM-41, with different concentrations of Lewis acidity have been prepared by the hydrothermal method. Physicochemical properties of all Fe-MCM-41 samples were obtained via HRTEM, PXRD and N 2 sorption characterization. The surface acidities were tested by NH 3 -TPD. The catalytic activity of all Fe-MCM-41 materials were evaluated in the acidolysis reaction of benzyl chloride with various fatty acids. The corresponding benzaldehyde and acyl chloride product were synthesized in good conversion and high atom efficiency over the catalyst with the highest Fe content.

KW - Acidolysis

KW - Coproduction

KW - Fe-MCM-41

KW - Lewis acid catalyst

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U2 - 10.1007/s10934-018-0645-9

DO - 10.1007/s10934-018-0645-9

M3 - 文章

AN - SCOPUS:85050623418

SN - 1380-2224

VL - 26

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EP - 269

JO - Journal of Porous Materials

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IS - 1

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Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid

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