La                         2                         O                         3                          nanoplate: An efficient electrocatalyst for artificial N                         2                          fixation to NH                         3                          with excellent selectivity at ambient condition

Bo Xu; Zaichun Liu; Weibin Qiu; Qian Liu; Xuping Sun; Guanwei Cui; Yuping Wu; Xiaoli Xiong

doi:10.1016/j.electacta.2018.12.084

La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition

Bo Xu, Zaichun Liu, Weibin Qiu, Qian Liu, Xuping Sun, Guanwei Cui, Yuping Wu, Xiaoli Xiong

能源科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

42 引用（Scopus）

摘要

Identification of new effective and selective N ₂ reduction electrocatalyst is still of critical importance for fundamental and application research. Here, we report La ₂ O ₃ nanoplate performing as an efficient metal oxide catalyst for electrochemical N ₂ fixation to NH ₃ , which exhibits excellent selectivity and stability with a high Faradaic efficiency of 4.76% and a NH ₃ yield rate of 17.04 μg h ⁻¹ mg ⁻¹ _cat. at −0.8 V vs. reversible hydrogen electrode (RHE) in 0.1 M Na ₂ SO ₄ solution under atmospheric pressure. Density functional theory (DFT) calculation results show that La atoms in La ₂ O ₃ act as the active sites for efficiently adsorbing N ₂ . The optimal adsorption approach of N ₂ molecule on the (011) face of La ₂ O ₃ is end-on-two configuration which is highly activated. Thus La ₂ O ₃ exhibits high performance for electrochemical reduction of N ₂ .

源语言	英语
页（从-至）	106-111
页数	6
期刊	Electrochimica Acta
卷	298
DOI	https://doi.org/10.1016/j.electacta.2018.12.084
出版状态	已出版 - 1 3月 2019

访问文件

10.1016/j.electacta.2018.12.084

其它文件与链接

链接到 Scopus 的出版物

引用此

Xu, B., Liu, Z., Qiu, W., Liu, Q., Sun, X., Cui, G., Wu, Y., & Xiong, X. (2019). La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition. Electrochimica Acta, 298, 106-111. https://doi.org/10.1016/j.electacta.2018.12.084

Xu, Bo ; Liu, Zaichun ; Qiu, Weibin 等. / La ₂ O ₃ nanoplate : An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition. 在: Electrochimica Acta. 2019 ; 卷 298. 页码 106-111.

@article{d293e8322eac46dd9de86c6447552926,

title = "La 2 O 3 nanoplate: An efficient electrocatalyst for artificial N 2 fixation to NH 3 with excellent selectivity at ambient condition",

abstract = " Identification of new effective and selective N 2 reduction electrocatalyst is still of critical importance for fundamental and application research. Here, we report La 2 O 3 nanoplate performing as an efficient metal oxide catalyst for electrochemical N 2 fixation to NH 3 , which exhibits excellent selectivity and stability with a high Faradaic efficiency of 4.76% and a NH 3 yield rate of 17.04 μg h −1 mg −1 cat. at −0.8 V vs. reversible hydrogen electrode (RHE) in 0.1 M Na 2 SO 4 solution under atmospheric pressure. Density functional theory (DFT) calculation results show that La atoms in La 2 O 3 act as the active sites for efficiently adsorbing N 2 . The optimal adsorption approach of N 2 molecule on the (011) face of La 2 O 3 is end-on-two configuration which is highly activated. Thus La 2 O 3 exhibits high performance for electrochemical reduction of N 2 .",

keywords = "Catalyst, Electrolysis, La O nanoplate, N reduction reaction",

author = "Bo Xu and Zaichun Liu and Weibin Qiu and Qian Liu and Xuping Sun and Guanwei Cui and Yuping Wu and Xiaoli Xiong",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

year = "2019",

month = mar,

day = "1",

doi = "10.1016/j.electacta.2018.12.084",

language = "英语",

volume = "298",

pages = "106--111",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd",

}

Xu, B, Liu, Z, Qiu, W, Liu, Q, Sun, X, Cui, G, Wu, Y & Xiong, X 2019, 'La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition', Electrochimica Acta, 卷 298, 页码 106-111. https://doi.org/10.1016/j.electacta.2018.12.084

La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition. / Xu, Bo; Liu, Zaichun; Qiu, Weibin 等.
在: Electrochimica Acta, 卷 298, 01.03.2019, 页码 106-111.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - La 2 O 3 nanoplate

T2 - An efficient electrocatalyst for artificial N 2 fixation to NH 3 with excellent selectivity at ambient condition

AU - Xu, Bo

AU - Liu, Zaichun

AU - Qiu, Weibin

AU - Liu, Qian

AU - Sun, Xuping

AU - Cui, Guanwei

AU - Wu, Yuping

AU - Xiong, Xiaoli

PY - 2019/3/1

Y1 - 2019/3/1

N2 - Identification of new effective and selective N 2 reduction electrocatalyst is still of critical importance for fundamental and application research. Here, we report La 2 O 3 nanoplate performing as an efficient metal oxide catalyst for electrochemical N 2 fixation to NH 3 , which exhibits excellent selectivity and stability with a high Faradaic efficiency of 4.76% and a NH 3 yield rate of 17.04 μg h −1 mg −1 cat. at −0.8 V vs. reversible hydrogen electrode (RHE) in 0.1 M Na 2 SO 4 solution under atmospheric pressure. Density functional theory (DFT) calculation results show that La atoms in La 2 O 3 act as the active sites for efficiently adsorbing N 2 . The optimal adsorption approach of N 2 molecule on the (011) face of La 2 O 3 is end-on-two configuration which is highly activated. Thus La 2 O 3 exhibits high performance for electrochemical reduction of N 2 .

AB - Identification of new effective and selective N 2 reduction electrocatalyst is still of critical importance for fundamental and application research. Here, we report La 2 O 3 nanoplate performing as an efficient metal oxide catalyst for electrochemical N 2 fixation to NH 3 , which exhibits excellent selectivity and stability with a high Faradaic efficiency of 4.76% and a NH 3 yield rate of 17.04 μg h −1 mg −1 cat. at −0.8 V vs. reversible hydrogen electrode (RHE) in 0.1 M Na 2 SO 4 solution under atmospheric pressure. Density functional theory (DFT) calculation results show that La atoms in La 2 O 3 act as the active sites for efficiently adsorbing N 2 . The optimal adsorption approach of N 2 molecule on the (011) face of La 2 O 3 is end-on-two configuration which is highly activated. Thus La 2 O 3 exhibits high performance for electrochemical reduction of N 2 .

KW - Catalyst

KW - Electrolysis

KW - La O nanoplate

KW - N reduction reaction

UR - http://www.scopus.com/inward/record.url?scp=85059569667&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2018.12.084

DO - 10.1016/j.electacta.2018.12.084

M3 - 文章

AN - SCOPUS:85059569667

SN - 0013-4686

VL - 298

SP - 106

EP - 111

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Xu B, Liu Z, Qiu W, Liu Q, Sun X, Cui G 等. La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition. Electrochimica Acta. 2019 3月 1;298:106-111. doi: 10.1016/j.electacta.2018.12.084

La 2 O 3 nanoplate: An efficient electrocatalyst for artificial N 2 fixation to NH 3 with excellent selectivity at ambient condition

摘要

访问文件

其它文件与链接

指纹

引用此

La ₂ O ₃ nanoplate: An efficient electrocatalyst for artificial N ₂ fixation to NH ₃ with excellent selectivity at ambient condition