Ligand-stabilized [P 4] 2+ cations

Maximilian Donath, Eamonn Conrad, Paul Jerabek, Gernot Frenking, Roland Fröhlich, Neil Burford, Jan J. Weigand

科研成果: 期刊稿件文章同行评审

50 引用 (Scopus)

摘要

The bis(triphenylarsane) complex of the [P 4] 2+ dication has been formed in a high-yielding one-pot synthesis. X-ray crystallography reveals a butterfly structure of the bicyclo[1.1.0]- tetraphosphane-1,4-diium core, with two triphenylarsane ligands in an exo,exo configuration (see picture). The reaction of [(Ph 3As) 2P 4] 2+ with Ph 3P results in the quantitative formation of [(Ph 3P) 2P 4] 2+ and Ph 3As.

源语言英语
页(从-至)2964-2967
页数4
期刊Angewandte Chemie - International Edition
51
12
DOI
出版状态已出版 - 19 3月 2012
已对外发布

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