摘要
The bis(triphenylarsane) complex of the [P 4] 2+ dication has been formed in a high-yielding one-pot synthesis. X-ray crystallography reveals a butterfly structure of the bicyclo[1.1.0]- tetraphosphane-1,4-diium core, with two triphenylarsane ligands in an exo,exo configuration (see picture). The reaction of [(Ph 3As) 2P 4] 2+ with Ph 3P results in the quantitative formation of [(Ph 3P) 2P 4] 2+ and Ph 3As.
源语言 | 英语 |
---|---|
页(从-至) | 2964-2967 |
页数 | 4 |
期刊 | Angewandte Chemie - International Edition |
卷 | 51 |
期 | 12 |
DOI | |
出版状态 | 已出版 - 19 3月 2012 |
已对外发布 | 是 |