Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties

Chixiao Ma; Wei Pan; Junyong Zhang; Xianghua Zeng; Chunhua Gong; Huiting Xu; Runpu Shen; Dun Ru Zhu; Jingli Xie

doi:10.1016/j.ica.2022.121166

Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties

Chixiao Ma, Wei Pan, Junyong Zhang, Xianghua Zeng, Chunhua Gong, Huiting Xu, Runpu Shen, Dun Ru Zhu, Jingli Xie

化工学院

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Two metal–organic frameworks, [Ag₂L(bpy)_0.5]_n (1) and [CoL(bpy)]_n (2), were successfully assembled through mixed-ligands strategy with different metal resource. Remarkably, both MOFs manifest multi-nuclear metal units as nodes and diverse topological structures. Compound 1 is an infinite two-dimensional layer structure with unsaturated four-nuclear silver unit nodes. While compound 2 exhibits a novel three-dimensional structure. The heterogeneous catalysis efficiency of the MOFs towards cycloaddition of N-methyl propargylamine with CO₂ has been explored, and compound 1 displays higher catalytic activity derived from bare Lewis acid silver active site.

源语言	英语
文章编号	121166
期刊	Inorganica Chimica Acta
卷	543
DOI	https://doi.org/10.1016/j.ica.2022.121166
出版状态	已出版 - 1 12月 2022

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title = "Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties",

abstract = "Two metal–organic frameworks, [Ag2L(bpy)0.5]n (1) and [CoL(bpy)]n (2), were successfully assembled through mixed-ligands strategy with different metal resource. Remarkably, both MOFs manifest multi-nuclear metal units as nodes and diverse topological structures. Compound 1 is an infinite two-dimensional layer structure with unsaturated four-nuclear silver unit nodes. While compound 2 exhibits a novel three-dimensional structure. The heterogeneous catalysis efficiency of the MOFs towards cycloaddition of N-methyl propargylamine with CO2 has been explored, and compound 1 displays higher catalytic activity derived from bare Lewis acid silver active site.",

keywords = "Heterogeneous catalysis, Metal–organic frameworks, Topological",

author = "Chixiao Ma and Wei Pan and Junyong Zhang and Xianghua Zeng and Chunhua Gong and Huiting Xu and Runpu Shen and Zhu, {Dun Ru} and Jingli Xie",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = dec,

day = "1",

doi = "10.1016/j.ica.2022.121166",

language = "英语",

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journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Metal-organic frameworks derived from chalcone dicarboxylic acid

T2 - New topological characters and initial catalytic properties

AU - Ma, Chixiao

AU - Pan, Wei

AU - Zhang, Junyong

AU - Zeng, Xianghua

AU - Gong, Chunhua

AU - Xu, Huiting

AU - Shen, Runpu

AU - Zhu, Dun Ru

AU - Xie, Jingli

PY - 2022/12/1

Y1 - 2022/12/1

N2 - Two metal–organic frameworks, [Ag2L(bpy)0.5]n (1) and [CoL(bpy)]n (2), were successfully assembled through mixed-ligands strategy with different metal resource. Remarkably, both MOFs manifest multi-nuclear metal units as nodes and diverse topological structures. Compound 1 is an infinite two-dimensional layer structure with unsaturated four-nuclear silver unit nodes. While compound 2 exhibits a novel three-dimensional structure. The heterogeneous catalysis efficiency of the MOFs towards cycloaddition of N-methyl propargylamine with CO2 has been explored, and compound 1 displays higher catalytic activity derived from bare Lewis acid silver active site.

AB - Two metal–organic frameworks, [Ag2L(bpy)0.5]n (1) and [CoL(bpy)]n (2), were successfully assembled through mixed-ligands strategy with different metal resource. Remarkably, both MOFs manifest multi-nuclear metal units as nodes and diverse topological structures. Compound 1 is an infinite two-dimensional layer structure with unsaturated four-nuclear silver unit nodes. While compound 2 exhibits a novel three-dimensional structure. The heterogeneous catalysis efficiency of the MOFs towards cycloaddition of N-methyl propargylamine with CO2 has been explored, and compound 1 displays higher catalytic activity derived from bare Lewis acid silver active site.

KW - Heterogeneous catalysis

KW - Metal–organic frameworks

KW - Topological

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U2 - 10.1016/j.ica.2022.121166

DO - 10.1016/j.ica.2022.121166

M3 - 文章

AN - SCOPUS:85138809281

SN - 0020-1693

VL - 543

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 121166

ER -

Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties

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