Modulating the basicity of Zn-MOF-74: Via cation exchange with calcium ions

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摘要

The fine-tuning of metal-based molecular building blocks in Zn-MOF-74 through post-synthetic cation exchange with Ca2+ significantly enhances its basicity and corresponding catalytic performance. The resulting material, exemplified by Ca/Zn-MOF-74, is shown through Knoevenagel condensation to give an improved product yield over the parent Zn-MOF-74 and Ni/Zn-MOF-74.

源语言英语
页(从-至)14971-14974
页数4
期刊Dalton Transactions
48
40
DOI
出版状态已出版 - 2019

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