Modulation of polyepoxysuccinic acid on crystallization of calcium oxalate

Yanqing Zhang; Yongming Tang; Jinqiu Xu; Dongqin Zhang; Gang Lu; Wenheng Jing

doi:10.1016/j.jssc.2015.08.001

Modulation of polyepoxysuccinic acid on crystallization of calcium oxalate

Yanqing Zhang, Yongming Tang, Jinqiu Xu, Dongqin Zhang, Gang Lu, Wenheng Jing

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

Abstract The influence of polyepoxysuccinic acid (PESA) on the phase composition and crystal morphology of calcium oxalate was investigated in this paper. It was found that the presence of PESA inhibited the growth of the monoclinic calcium oxalate monohydrate (COM) crystal and promoted the nucleation of the tetragonal calcium oxalate dihydrate (COD). In addition, with the increase in PESA concentration, the aggregation of COD crystals was reduced but the particle size was increased. Under the conditions of low calcium-to-oxalate ratio and high CaOx concentration, PESA could not effectively stabilize the formation of COD. Based on molecular dynamic simulations, the adsorption of PESA on CaOx crystal faces was confirmed.

源语言	英语
文章编号	19025
页（从-至）	7-12
页数	6
期刊	Journal of Solid State Chemistry
卷	231
DOI	https://doi.org/10.1016/j.jssc.2015.08.001
出版状态	已出版 - 11 8月 2015

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title = "Modulation of polyepoxysuccinic acid on crystallization of calcium oxalate",

abstract = "Abstract The influence of polyepoxysuccinic acid (PESA) on the phase composition and crystal morphology of calcium oxalate was investigated in this paper. It was found that the presence of PESA inhibited the growth of the monoclinic calcium oxalate monohydrate (COM) crystal and promoted the nucleation of the tetragonal calcium oxalate dihydrate (COD). In addition, with the increase in PESA concentration, the aggregation of COD crystals was reduced but the particle size was increased. Under the conditions of low calcium-to-oxalate ratio and high CaOx concentration, PESA could not effectively stabilize the formation of COD. Based on molecular dynamic simulations, the adsorption of PESA on CaOx crystal faces was confirmed.",

keywords = "Adsorption, Crystal growth, Crystal morphology, Polymer",

author = "Yanqing Zhang and Yongming Tang and Jinqiu Xu and Dongqin Zhang and Gang Lu and Wenheng Jing",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Inc.",

year = "2015",

month = aug,

day = "11",

doi = "10.1016/j.jssc.2015.08.001",

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TY - JOUR

T1 - Modulation of polyepoxysuccinic acid on crystallization of calcium oxalate

AU - Zhang, Yanqing

AU - Tang, Yongming

AU - Xu, Jinqiu

AU - Zhang, Dongqin

AU - Lu, Gang

AU - Jing, Wenheng

PY - 2015/8/11

Y1 - 2015/8/11

N2 - Abstract The influence of polyepoxysuccinic acid (PESA) on the phase composition and crystal morphology of calcium oxalate was investigated in this paper. It was found that the presence of PESA inhibited the growth of the monoclinic calcium oxalate monohydrate (COM) crystal and promoted the nucleation of the tetragonal calcium oxalate dihydrate (COD). In addition, with the increase in PESA concentration, the aggregation of COD crystals was reduced but the particle size was increased. Under the conditions of low calcium-to-oxalate ratio and high CaOx concentration, PESA could not effectively stabilize the formation of COD. Based on molecular dynamic simulations, the adsorption of PESA on CaOx crystal faces was confirmed.

AB - Abstract The influence of polyepoxysuccinic acid (PESA) on the phase composition and crystal morphology of calcium oxalate was investigated in this paper. It was found that the presence of PESA inhibited the growth of the monoclinic calcium oxalate monohydrate (COM) crystal and promoted the nucleation of the tetragonal calcium oxalate dihydrate (COD). In addition, with the increase in PESA concentration, the aggregation of COD crystals was reduced but the particle size was increased. Under the conditions of low calcium-to-oxalate ratio and high CaOx concentration, PESA could not effectively stabilize the formation of COD. Based on molecular dynamic simulations, the adsorption of PESA on CaOx crystal faces was confirmed.

KW - Adsorption

KW - Crystal growth

KW - Crystal morphology

KW - Polymer

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U2 - 10.1016/j.jssc.2015.08.001

DO - 10.1016/j.jssc.2015.08.001

M3 - 文章

AN - SCOPUS:84938811201

SN - 0022-4596

VL - 231

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EP - 12

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

M1 - 19025

ER -

Modulation of polyepoxysuccinic acid on crystallization of calcium oxalate

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