Novel composite polymer electrolytes based on poly(ether-urethane) network polymer and modified montmorillonite

X. J. Wang; J. J. Kang; Y. P. Wu; S. B. Fang

doi:10.1016/j.elecom.2003.09.018

Novel composite polymer electrolytes based on poly(ether-urethane) network polymer and modified montmorillonite

X. J. Wang, J. J. Kang, Y. P. Wu, S. B. Fang

CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

Novel composite solid polymer dectrolytes (CSPEs) and composite gel polymer electrolytes (CGPEs) have been prepared. CSPE consists of poly(ether-urethane) network polymer, which is superior to poly(ethylene oxide) in mechanical stability due to its crosslinked structure, modified montmorillonite (MMMT) and LiClO₄, and CGPE with good mechanical strength comprises of the CSPE and LiClO₄-PC (propylene carbonate) solution. The ionic conductivity can be enhanced after the addition of MMMT, and CGPE exhibits ionic conductivity in the order of 10^-3 S/cm at room temperature. The temperature dependence of the ionic conductivity of the CSPE follows the Vogel-Tamman-Fulcher (VTF) equation. The effects of MMMT on the interactions in these systems and the possible conduction mechanisms are also discussed.

源语言	英语
页（从-至）	1025-1029
页数	5
期刊	Electrochemistry Communications
卷	5
期	12
DOI	https://doi.org/10.1016/j.elecom.2003.09.018
出版状态	已出版 - 12月 2003
已对外发布	是

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title = "Novel composite polymer electrolytes based on poly(ether-urethane) network polymer and modified montmorillonite",

abstract = "Novel composite solid polymer dectrolytes (CSPEs) and composite gel polymer electrolytes (CGPEs) have been prepared. CSPE consists of poly(ether-urethane) network polymer, which is superior to poly(ethylene oxide) in mechanical stability due to its crosslinked structure, modified montmorillonite (MMMT) and LiClO4, and CGPE with good mechanical strength comprises of the CSPE and LiClO4-PC (propylene carbonate) solution. The ionic conductivity can be enhanced after the addition of MMMT, and CGPE exhibits ionic conductivity in the order of 10-3 S/cm at room temperature. The temperature dependence of the ionic conductivity of the CSPE follows the Vogel-Tamman-Fulcher (VTF) equation. The effects of MMMT on the interactions in these systems and the possible conduction mechanisms are also discussed.",

keywords = "Composite gel polymer electrolyte, Composite solid polymer electrolyte, Ionic conductivity, Modified montmorillonite, Poly(ether-urethane) network polymer",

author = "Wang, {X. J.} and Kang, {J. J.} and Wu, {Y. P.} and Fang, {S. B.}",

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AU - Wang, X. J.

AU - Kang, J. J.

AU - Wu, Y. P.

AU - Fang, S. B.

PY - 2003/12

Y1 - 2003/12

N2 - Novel composite solid polymer dectrolytes (CSPEs) and composite gel polymer electrolytes (CGPEs) have been prepared. CSPE consists of poly(ether-urethane) network polymer, which is superior to poly(ethylene oxide) in mechanical stability due to its crosslinked structure, modified montmorillonite (MMMT) and LiClO4, and CGPE with good mechanical strength comprises of the CSPE and LiClO4-PC (propylene carbonate) solution. The ionic conductivity can be enhanced after the addition of MMMT, and CGPE exhibits ionic conductivity in the order of 10-3 S/cm at room temperature. The temperature dependence of the ionic conductivity of the CSPE follows the Vogel-Tamman-Fulcher (VTF) equation. The effects of MMMT on the interactions in these systems and the possible conduction mechanisms are also discussed.

AB - Novel composite solid polymer dectrolytes (CSPEs) and composite gel polymer electrolytes (CGPEs) have been prepared. CSPE consists of poly(ether-urethane) network polymer, which is superior to poly(ethylene oxide) in mechanical stability due to its crosslinked structure, modified montmorillonite (MMMT) and LiClO4, and CGPE with good mechanical strength comprises of the CSPE and LiClO4-PC (propylene carbonate) solution. The ionic conductivity can be enhanced after the addition of MMMT, and CGPE exhibits ionic conductivity in the order of 10-3 S/cm at room temperature. The temperature dependence of the ionic conductivity of the CSPE follows the Vogel-Tamman-Fulcher (VTF) equation. The effects of MMMT on the interactions in these systems and the possible conduction mechanisms are also discussed.

KW - Composite gel polymer electrolyte

KW - Composite solid polymer electrolyte

KW - Ionic conductivity

KW - Modified montmorillonite

KW - Poly(ether-urethane) network polymer

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VL - 5

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JO - Electrochemistry Communications

JF - Electrochemistry Communications

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ER -

Novel composite polymer electrolytes based on poly(ether-urethane) network polymer and modified montmorillonite

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