Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

Luan Ying Li, Bo Rong Leng, Jia Zhuo Li, Qing Quan Liu, Jianguang Yu, Ping Wei, De Cai Wang, Yi Long Zhu

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.

源语言英语
页(从-至)8443-8448
页数6
期刊RSC Advances
12
14
DOI
出版状态已出版 - 18 3月 2022

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