Polycyclic heteroaromatic ring construction driven by silver/cobalt co-catalyzed desulfonylative and defluorinative fragment-recombination of enol nonaflates with amidines

Ting Xie, Yao Wei Zhang, Li Li Liu, Zhi Liang Shen, Teck Peng Loh, Xue Qiang Chu

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21 引用 (Scopus)

摘要

We present a Ag(i)/Co(ii) co-catalyzed tandem fragmentation and recombination reaction commencing from detachable nonaflates and amidines. This catalytic method offers a unique and expeditious access to various fluoroalkylated dihydrobenzo[h]quinazolines and benzo[h]quinazolines in the absence of external fluorine sources through a rationally designed radical desulfonylation, migration, defluorination, and polar condensation relay.

源语言英语
页(从-至)12722-12725
页数4
期刊Chemical Communications
54
90
DOI
出版状态已出版 - 2018

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