Preparation and facile addition reactions of iminium salts derived from amino ketene silyl acetal and amino silyl enol ether

Makoto Shimizu, Shingo Hata, Koichi Kondo, Kazuhiro Murakami, Isao Mizota, Yusong Zhu

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

While iminium salts generated by the oxidation of amino ketene silyl acetals show intriguing reactivities to give useful γ-oxo-α-amino esters via reactions with silyl enol ethers in good yields, new iminium salts are also prepared by the oxidation of amino silyl enol ethers. They undergo facile addition reaction with various nucleophiles to give α-amino ketone derivatives in good yields.

源语言英语
页(从-至)27874-27883
页数10
期刊RSC Advances
10
46
DOI
出版状态已出版 - 20 7月 2020

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