@article{e96962ef575744539d681c856eeac826,
title = "Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates: Highly diastereoselective synthesis of trans-diamines from cycloalkenes",
abstract = "Metal-free synthesis: Diamination of alkenes by using phenylhydrazine and azodicarboxylates could be achieved in a one-pot manner under very mild conditions (see scheme; Boc=tert-butoxycarbonyl). This process works with the assistance of acetic acid by means of a radical mechanism and displays a high trans selectivity when cycloalkene substrates were used in the reaction.",
keywords = "alkenes, cyclization, diamination, diastereoselectivity, radicals",
author = "Zhu, {Ming Kui} and Chen, {Yu Chen} and Loh, {Teck Peng}",
year = "2013",
month = apr,
day = "22",
doi = "10.1002/chem.201203832",
language = "英语",
volume = "19",
pages = "5250--5254",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "John Wiley and Sons Inc",
number = "17",
}