Reductive elimination: A pathway to low-valent aluminium species

Chelladurai Ganesamoorthy; Sinah Loerke; Christian Gemel; Paul Jerabek; Manuela Winter; Gernot Frenking; Roland A. Fischer

doi:10.1039/c3cc38584a

Reductive elimination: A pathway to low-valent aluminium species

Chelladurai Ganesamoorthy, Sinah Loerke, Christian Gemel, Paul Jerabek, Manuela Winter, Gernot Frenking, Roland A. Fischer

Ruhr University Bochum

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82 引用（Scopus）

摘要

Compounds Cp*AlH₂(1) and Cp*₂AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

源语言	英语
页（从-至）	2858-2860
页数	3
期刊	Chemical Communications
卷	49
期	28
DOI	https://doi.org/10.1039/c3cc38584a
出版状态	已出版 - 12 3月 2013
已对外发布	是

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title = "Reductive elimination: A pathway to low-valent aluminium species",

abstract = "Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.",

author = "Chelladurai Ganesamoorthy and Sinah Loerke and Christian Gemel and Paul Jerabek and Manuela Winter and Gernot Frenking and Fischer, {Roland A.}",

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AU - Ganesamoorthy, Chelladurai

AU - Loerke, Sinah

AU - Gemel, Christian

AU - Jerabek, Paul

AU - Winter, Manuela

AU - Frenking, Gernot

AU - Fischer, Roland A.

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N2 - Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

AB - Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

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Reductive elimination: A pathway to low-valent aluminium species

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