Regioselective and Geometrically Controlled Heck 1,1-Diarylation of Unactivated Aliphatic Alkenes

Yao Zhao, Shuangqiang Wang, Huihui Shao, Xuyong Tan, Rizhi Chen, Teck Peng Loh, Jianrong Steve Zhou, Xiaojin Wu

科研成果: 期刊稿件文章同行评审

5 引用 (Scopus)

摘要

Pd-catalyzed double Heck reaction allows regioselective 1,1-diarylation of unactivated aliphatic alkenes. When two different aryl bromides are used, the second aryl rings are added trans to aliphatic chains in the main olefinic isomers, consistent with a mechanism of two consecutive Heck arylations at the terminal carbons.

源语言英语
页(从-至)4258-4263
页数6
期刊Organic Letters
25
23
DOI
出版状态已出版 - 16 6月 2023

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