摘要
A method has been developed to suppress the decomposition of propylene carbonate (PC) by coating graphite electrode foil with a layer of silver. Results from electrochemical impedance measurements show that the Ag-coated graphite electrode presents lower charge transfer resistance and faster diffusion of lithium ions in comparison with the virginal one. Cyclic voltammograms and discharge-charge measurements suggest that the decomposition of propylene carbonate and co-intercalation of solvated lithium ions are prevented, and lithium ions can reversibly intercalate into and deintercalate from the Ag-coated graphite electrode. These results indicate that Ag-coating is a good way to improve the electrochemical performance of graphitic carbon in PC-based electrolyte solutions.
源语言 | 英语 |
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页(从-至) | 1380-1384 |
页数 | 5 |
期刊 | Electrochimica Acta |
卷 | 53 |
期 | 3 SPEC. ISS. |
DOI | |
出版状态 | 已出版 - 20 12月 2007 |
已对外发布 | 是 |