Resource utilization of high-concentration SO₂ for sulfur production over La-Ce-O_x composite oxide catalyst

Sulfur dioxide is one of the main causes of air pollution such as acid rain and photochemical smog, and its pollution control and resource utilization have become important research directions. La₂O₃ was incorporated into CeO₂ to enhance the surface basicity of La-Ce-O_x catalyst and increase the concentration of chemisorbed oxygen, thereby promoting the improvement of catalytic performance of SO₂ reduction by CO. Results have showed that the incorporation of La₂O₃ would not only increase the concentration of chemisorbed oxygen and hydroxyl on the catalyst surface, but also increase the basicity of the catalyst, thereby facilitating the adsorption of SO₂ on the catalyst surface. The 12%La-Ce-O_x was the optimal catalyst, and its SO₂ conversion at 350–400 ℃ reached close to 100%, and the sulfur yield at this temperature range was higher than 93%. Finally, according to the in situ infrared diffuse reflectance spectrum, it was found that the main reaction intermediates of 12%La-Ce-O_x in the catalytic reduction of SO₂ were weakly adsorbed sulfate, SO₃²⁻, non-coordinating CO₃²⁻, monodentate carbonate, and CO, so the catalytic reaction followed the L–H and E-R mechanisms simultaneously.