Screen-printing of core-shell Mn₃O₄@C nanocubes based sensing microchip performing ultrasensitive recognition of allura red

Allura red (AR) is a member of azo dyes is commonly used as an additive in foods and soft drinks. However, due to the special harm of the azo structure to the human body, the dosage control of AR becomes particularly necessary. The present detection methods are time-consuming, expensive and complicated. In order to address the above issues, a core-shell nanocubes constructed sensor has been developed to determine the ultrawide detection range and selective recognition of AR with a long-term reusability. The core-shell architecture is composed of carbon material of 12.64 nm thickness covering 600 nm Mn₃O₄ nanocube. This nanocomposite combines the advantages of Mn₃O₄@C, possessing high electrocatalysis and chemical stability. As confirmed in using sports drinks as real samples, the as-prepared AR sensor exhibites excellent selectivity with an ultra-wide linear range from 0.1 to 1748.4 μM, and meanwhile, this sensor can also meet the requirements of remarkable anti-interference and reusability over 30 days.