Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium

René Wollert; Antje Höllwarth; Gernot Frenking; Dieter Fenske; Helmut Goesmann; Kurt Dehnicke

doi:10.1002/anie.199212511

Se₂NCl₃ and [Se₂NCl₂]⁺ [GaCl₄]⁻, Chloride Nitrides of Trivalent Selenium

René Wollert, Antje Höllwarth, Gernot Frenking, Dieter Fenske, Helmut Goesmann, Kurt Dehnicke

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

The planar structure with C_2v symmetry resembles a compass in the case of Se₂NCl₃ (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl₃ to form [Se₂NCl₂][GaCl₄] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

源语言	英语
页（从-至）	1251-1253
页数	3
期刊	Angewandte Chemie - International Edition
卷	31
期	9
DOI	https://doi.org/10.1002/anie.199212511
出版状态	已出版 - 9月 1992
已对外发布	是

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title = "Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium",

abstract = "The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)",

author = "Ren{\'e} Wollert and Antje H{\"o}llwarth and Gernot Frenking and Dieter Fenske and Helmut Goesmann and Kurt Dehnicke",

year = "1992",

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doi = "10.1002/anie.199212511",

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T1 - Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium

AU - Wollert, René

AU - Höllwarth, Antje

AU - Frenking, Gernot

AU - Fenske, Dieter

AU - Goesmann, Helmut

AU - Dehnicke, Kurt

PY - 1992/9

Y1 - 1992/9

N2 - The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

AB - The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

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U2 - 10.1002/anie.199212511

DO - 10.1002/anie.199212511

M3 - 文章

AN - SCOPUS:33748214272

SN - 1433-7851

VL - 31

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EP - 1253

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium

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Se₂NCl₃ and [Se₂NCl₂]⁺ [GaCl₄]⁻, Chloride Nitrides of Trivalent Selenium