Site-selective C(sp3)-H amination of thioamide with anthranils under Cp∗CoIII catalysis

Rui Hua Liu; Qi Chao Shan; Xu Hong Hu; Teck Peng Loh

doi:10.1039/c9cc01715a

Site-selective C(sp³)-H amination of thioamide with anthranils under Cp∗Co^III catalysis

Rui Hua Liu, Qi Chao Shan, Xu Hong Hu, Teck Peng Loh

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

46 引用（Scopus）

摘要

Synthetically versatile anthranils as a bifunctional amino source have been employed for the first time to enable direct amination on unactivated C(sp³)-H bonds of thioamides under Cp∗Co^III catalysis. The excellent site-selectivity on primary C(sp³)-H bonds is observed for a diverse array of thioamides with high functional group tolerance. Further applicability of the products is also highlighted through a series of interesting synthetic elaborations.

源语言	英语
页（从-至）	5519-5522
页数	4
期刊	Chemical Communications
卷	55
期	38
DOI	https://doi.org/10.1039/c9cc01715a
出版状态	已出版 - 2019

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10.1039/c9cc01715a

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AU - Loh, Teck Peng

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Y1 - 2019

N2 - Synthetically versatile anthranils as a bifunctional amino source have been employed for the first time to enable direct amination on unactivated C(sp3)-H bonds of thioamides under Cp∗CoIII catalysis. The excellent site-selectivity on primary C(sp3)-H bonds is observed for a diverse array of thioamides with high functional group tolerance. Further applicability of the products is also highlighted through a series of interesting synthetic elaborations.

AB - Synthetically versatile anthranils as a bifunctional amino source have been employed for the first time to enable direct amination on unactivated C(sp3)-H bonds of thioamides under Cp∗CoIII catalysis. The excellent site-selectivity on primary C(sp3)-H bonds is observed for a diverse array of thioamides with high functional group tolerance. Further applicability of the products is also highlighted through a series of interesting synthetic elaborations.

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Site-selective C(sp3)-H amination of thioamide with anthranils under Cp∗CoIII catalysis

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Site-selective C(sp³)-H amination of thioamide with anthranils under Cp∗Co^III catalysis