Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone

Ning Zhu; Zilong Zhang; Weiyang Feng; Yuqiang Zeng; Zhongyue Li; Zheng Fang; Kai Zhang; Zhenjiang Li; Kai Guo

doi:10.1039/c5ra02583d

Sn(OTf)₂ catalyzed continuous flow ring-opening polymerization of ε-caprolactone

Ning Zhu, Zilong Zhang, Weiyang Feng, Yuqiang Zeng, Zhongyue Li, Zheng Fang, Kai Zhang, Zhenjiang Li, Kai Guo

生物与制药工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

22 引用（Scopus）

摘要

A simple PTFE tubular microreactor based platform was developed to conduct metal-catalytic ring-opening polymerization of cyclic monomers. Sn(OTf)₂ catalyzed ε-caprolactone polymerization with benzyl alcohol as initiator was the model system for investigation. In contrast to the batch reactor, better control of reaction conditions, faster polymerizations and narrower molecular weight distributions of resultant poly(ε-caprolactone) were achieved in the continuous flow mode. The structure of the product was characterized by ¹H NMR, SEC and MALDI TOF MS. The kinetic study elucidated the living/control nature of Sn(OTf)₂ catalyzed continuous flow ring-opening polymerization of ε-caprolactone.

源语言	英语
页（从-至）	31554-31557
页数	4
期刊	RSC Advances
卷	5
期	40
DOI	https://doi.org/10.1039/c5ra02583d
出版状态	已出版 - 2015

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10.1039/c5ra02583d

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title = "Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone",

abstract = "A simple PTFE tubular microreactor based platform was developed to conduct metal-catalytic ring-opening polymerization of cyclic monomers. Sn(OTf)2 catalyzed ε-caprolactone polymerization with benzyl alcohol as initiator was the model system for investigation. In contrast to the batch reactor, better control of reaction conditions, faster polymerizations and narrower molecular weight distributions of resultant poly(ε-caprolactone) were achieved in the continuous flow mode. The structure of the product was characterized by 1H NMR, SEC and MALDI TOF MS. The kinetic study elucidated the living/control nature of Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone.",

author = "Ning Zhu and Zilong Zhang and Weiyang Feng and Yuqiang Zeng and Zhongyue Li and Zheng Fang and Kai Zhang and Zhenjiang Li and Kai Guo",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c5ra02583d",

language = "英语",

volume = "5",

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T1 - Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone

AU - Zhu, Ning

AU - Zhang, Zilong

AU - Feng, Weiyang

AU - Zeng, Yuqiang

AU - Li, Zhongyue

AU - Fang, Zheng

AU - Zhang, Kai

AU - Li, Zhenjiang

AU - Guo, Kai

PY - 2015

Y1 - 2015

N2 - A simple PTFE tubular microreactor based platform was developed to conduct metal-catalytic ring-opening polymerization of cyclic monomers. Sn(OTf)2 catalyzed ε-caprolactone polymerization with benzyl alcohol as initiator was the model system for investigation. In contrast to the batch reactor, better control of reaction conditions, faster polymerizations and narrower molecular weight distributions of resultant poly(ε-caprolactone) were achieved in the continuous flow mode. The structure of the product was characterized by 1H NMR, SEC and MALDI TOF MS. The kinetic study elucidated the living/control nature of Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone.

AB - A simple PTFE tubular microreactor based platform was developed to conduct metal-catalytic ring-opening polymerization of cyclic monomers. Sn(OTf)2 catalyzed ε-caprolactone polymerization with benzyl alcohol as initiator was the model system for investigation. In contrast to the batch reactor, better control of reaction conditions, faster polymerizations and narrower molecular weight distributions of resultant poly(ε-caprolactone) were achieved in the continuous flow mode. The structure of the product was characterized by 1H NMR, SEC and MALDI TOF MS. The kinetic study elucidated the living/control nature of Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone.

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U2 - 10.1039/c5ra02583d

DO - 10.1039/c5ra02583d

M3 - 文章

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SN - 2046-2069

VL - 5

SP - 31554

EP - 31557

JO - RSC Advances

JF - RSC Advances

IS - 40

ER -

Sn(OTf)2 catalyzed continuous flow ring-opening polymerization of ε-caprolactone

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Sn(OTf)₂ catalyzed continuous flow ring-opening polymerization of ε-caprolactone