TY - JOUR
T1 - Solvothermal synthesis and structural characterization of an organic-Templated new aluminogermanate with the GIS topology
AU - Sun, Xiaochang
AU - Liu, Yanbo
AU - Chen, Qi
AU - Liu, Bing
AU - Zhu, Dunru
AU - Xu, Yan
PY - 2009/12
Y1 - 2009/12
N2 - A new organic-templated aluminogermanate [C4H12N]- [AlGe3O8](1) has been prepared under solvothermal conditions by using 2-propanol as solvent. The structure of the title compound was characterized by IR spectroscopic, elemental analysis, TG, single-crystal X-ray diffraction and powder X-ray diffraction. Compound 1 crystallizes in the tetragonal space group I41/a, a=b=10.7754(8) Å, c=.9116(14) Å, V=1150.8(2) Å3, Z =4. The structure of the title compound shows eight-membered ring channels along a and b axes with a typical GIS topology, and- most importantly-the structure of the inorganic framework is retained when the organic amine is removed by calcination.© 2009 WILEYVCH Verlag GmbH & Co. KGaA.
AB - A new organic-templated aluminogermanate [C4H12N]- [AlGe3O8](1) has been prepared under solvothermal conditions by using 2-propanol as solvent. The structure of the title compound was characterized by IR spectroscopic, elemental analysis, TG, single-crystal X-ray diffraction and powder X-ray diffraction. Compound 1 crystallizes in the tetragonal space group I41/a, a=b=10.7754(8) Å, c=.9116(14) Å, V=1150.8(2) Å3, Z =4. The structure of the title compound shows eight-membered ring channels along a and b axes with a typical GIS topology, and- most importantly-the structure of the inorganic framework is retained when the organic amine is removed by calcination.© 2009 WILEYVCH Verlag GmbH & Co. KGaA.
KW - Aluminum
KW - Germanium
KW - Solid-state structures
KW - Thermal stability
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=72949115105&partnerID=8YFLogxK
U2 - 10.1002/zaac.200900142
DO - 10.1002/zaac.200900142
M3 - 文章
AN - SCOPUS:72949115105
SN - 0044-2313
VL - 635
SP - 2596
EP - 2600
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 15
ER -