Spatially confined growth of carbon nanotubes in the pore channels of microporous ceramic supports with improved filtration efficiency

Carbon nanotubes (CNTs) with high degrees of uniformity, orientation and controlled dimensions on porous supports are highly desirable for various applications such as separation of O/W emulsions and air purification. In this work, CNTs were fabricated on silicon carbide (SiC) porous supports with different porosities and pore sizes by chemical vapor deposition (CVD). The growth processes of CNTs on the surface and in the pore channels of the SiC support were studied in detail. Based on microstructural characterization by SEM, Raman spectroscopy and TEM, it was found that these CNTs grown in the pore channels of SiC supports had a higher degree of orientation and purity than those grown on the surface due to the spatially confined effect. The growth processes of various types of CNTs on the microporous supports were proposed, which were further verified by CNTs with different steric configurations (S-CNTs and VACNTs) and on Al₂O₃ porous supports. Moreover, the contribution of CNTs in the pore channels to the filtration efficiency was demonstrated in oil-water emulsion separation and particle removal in air. This work provides significant guidance for the preparation and filtration application of CNTs on porous materials.