Spirobis(pentagerma[1.1.1]propellane): A stable tetraradicaloid

Yuki Ito; Vladimir Ya Lee; Heinz Gornitzka; Catharina Goedecke; Gernot Frenking; Akira Sekiguchi

doi:10.1021/ja401650q

Spirobis(pentagerma[1.1.1]propellane): A stable tetraradicaloid

Yuki Ito, Vladimir Ya Lee, Heinz Gornitzka, Catharina Goedecke, Gernot Frenking, Akira Sekiguchi

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39 引用（Scopus）

摘要

In this contribution, we report a spirobis(pentagerma[1.1.1]propellane) derivative as a novel type of molecular architecture in cluster chemistry that features two spiro-fused [1.1.1]propellane units and represents a stable tetraradicaloid species. The crucial issue of the nature of the interaction between the germanium bridgeheads was probed computationally, revealing weak bonding interactions between the formally unpaired electrons.

源语言	英语
页（从-至）	6770-6773
页数	4
期刊	Journal of the American Chemical Society
卷	135
期	18
DOI	https://doi.org/10.1021/ja401650q
出版状态	已出版 - 8 5月 2013
已对外发布	是

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AU - Frenking, Gernot

AU - Sekiguchi, Akira

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Spirobis(pentagerma[1.1.1]propellane): A stable tetraradicaloid

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