Stereoselective synthesis of β-amino hydroxylamines

Manfred T. Reetz; Dirk Röhrig; Klaus Harms; Gernot Frenking

doi:10.1016/S0040-4039(00)78492-9

Stereoselective synthesis of β-amino hydroxylamines

Manfred T. Reetz, Dirk Röhrig, Klaus Harms, Gernot Frenking

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29 引用（Scopus）

摘要

Chiral γ-N,N-dibenzylamino-substituted α,β-unsaturated carboxylic acid esters and dicarboxylic acid esters, prepared in enantiomerically pure form from L-amino acids, undergo diastereoselective Michael addition reactions with nitrogen nucleophiles of the type Me₃SiNHOSiMe₃ and CH₃NHOH; the products are novel β-amino hydroxylamine derivatives having two defined stereogenic centers.

源语言	英语
页（从-至）	8765-8768
页数	4
期刊	Tetrahedron Letters
卷	35
期	47
DOI	https://doi.org/10.1016/S0040-4039(00)78492-9
出版状态	已出版 - 21 11月 1994
已对外发布	是

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AU - Reetz, Manfred T.

AU - Röhrig, Dirk

AU - Harms, Klaus

AU - Frenking, Gernot

PY - 1994/11/21

Y1 - 1994/11/21

N2 - Chiral γ-N,N-dibenzylamino-substituted α,β-unsaturated carboxylic acid esters and dicarboxylic acid esters, prepared in enantiomerically pure form from L-amino acids, undergo diastereoselective Michael addition reactions with nitrogen nucleophiles of the type Me3SiNHOSiMe3 and CH3NHOH; the products are novel β-amino hydroxylamine derivatives having two defined stereogenic centers.

AB - Chiral γ-N,N-dibenzylamino-substituted α,β-unsaturated carboxylic acid esters and dicarboxylic acid esters, prepared in enantiomerically pure form from L-amino acids, undergo diastereoselective Michael addition reactions with nitrogen nucleophiles of the type Me3SiNHOSiMe3 and CH3NHOH; the products are novel β-amino hydroxylamine derivatives having two defined stereogenic centers.

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U2 - 10.1016/S0040-4039(00)78492-9

DO - 10.1016/S0040-4039(00)78492-9

M3 - 文章

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JF - Tetrahedron Letters

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ER -

Stereoselective synthesis of β-amino hydroxylamines

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