Study and fabrication of lithium ion batteries using tris (methoxypolyethyleneglycol) aluminate esters as plasticizer for polymer electrolyte

Feng Cai; Xiang Zuo; Long Wang; Wei Zhai; Xiao Ming Liu; Hui Yang; Yu Jun Shi

doi:10.3969/j.issn.1001-9731.2013.19.023

Study and fabrication of lithium ion batteries using tris (methoxypolyethyleneglycol) aluminate esters as plasticizer for polymer electrolyte

Feng Cai, Xiang Zuo, Long Wang, Wei Zhai, Xiao Ming Liu, Hui Yang, Yu Jun Shi

材料科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A novel comb-like copolymer electrolyte was designed by co-polymerizing of two macro-monomers: methoxy-poly (ethylene glycol) methacrylate (MPEGM) and hexadecal-poly (ethylene glycol) methacrylate (HPEGM), tris (methoxypolyethyleneglycol) aluminate ester (MPEG-Al ester), Li-salt (LiClO₄). Performances of the polymer electrolytes were studied by FT-IR, DSC and alternating current (AC) impedance and so on. The results showed that P (MPEGM-HPEGM) had been formed and the motion of PEO chains had been improved. The polymer electrolytes possessed excellent thermal stability and electrochemical stability. And when the weight ratio of MPEGM to HPEGM to MPEG₇-Al ester was 4:1:5, the maximum ionic conductivity value reached 0.43 × 10^-3S/cm with n (Li⁺): n (EO) =1:20 at 30°C.

源语言	英语
页（从-至）	2844-2848
页数	5
期刊	Gongneng Cailiao/Journal of Functional Materials
卷	44
期	19
DOI	https://doi.org/10.3969/j.issn.1001-9731.2013.19.023
出版状态	已出版 - 2013

联合国可持续发展目标

此成果有助于实现下列可持续发展目标：

访问文件

10.3969/j.issn.1001-9731.2013.19.023

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{06b189073c8b4eb089f9baad6556dc30,

title = "Study and fabrication of lithium ion batteries using tris (methoxypolyethyleneglycol) aluminate esters as plasticizer for polymer electrolyte",

abstract = "A novel comb-like copolymer electrolyte was designed by co-polymerizing of two macro-monomers: methoxy-poly (ethylene glycol) methacrylate (MPEGM) and hexadecal-poly (ethylene glycol) methacrylate (HPEGM), tris (methoxypolyethyleneglycol) aluminate ester (MPEG-Al ester), Li-salt (LiClO4). Performances of the polymer electrolytes were studied by FT-IR, DSC and alternating current (AC) impedance and so on. The results showed that P (MPEGM-HPEGM) had been formed and the motion of PEO chains had been improved. The polymer electrolytes possessed excellent thermal stability and electrochemical stability. And when the weight ratio of MPEGM to HPEGM to MPEG7-Al ester was 4:1:5, the maximum ionic conductivity value reached 0.43 × 10-3S/cm with n (Li+): n (EO) =1:20 at 30°C.",

keywords = "Comb-like copolymer, Ionic conductivity, MPEG-Al ester, Solid polymer electrolyte",

author = "Feng Cai and Xiang Zuo and Long Wang and Wei Zhai and Liu, {Xiao Ming} and Hui Yang and Shi, {Yu Jun}",

year = "2013",

doi = "10.3969/j.issn.1001-9731.2013.19.023",

language = "英语",

volume = "44",

pages = "2844--2848",

journal = "Gongneng Cailiao/Journal of Functional Materials",

issn = "1001-9731",

publisher = "Journal of Functional Materials",

number = "19",

}

TY - JOUR

T1 - Study and fabrication of lithium ion batteries using tris (methoxypolyethyleneglycol) aluminate esters as plasticizer for polymer electrolyte

AU - Cai, Feng

AU - Zuo, Xiang

AU - Wang, Long

AU - Zhai, Wei

AU - Liu, Xiao Ming

AU - Yang, Hui

AU - Shi, Yu Jun

PY - 2013

Y1 - 2013

N2 - A novel comb-like copolymer electrolyte was designed by co-polymerizing of two macro-monomers: methoxy-poly (ethylene glycol) methacrylate (MPEGM) and hexadecal-poly (ethylene glycol) methacrylate (HPEGM), tris (methoxypolyethyleneglycol) aluminate ester (MPEG-Al ester), Li-salt (LiClO4). Performances of the polymer electrolytes were studied by FT-IR, DSC and alternating current (AC) impedance and so on. The results showed that P (MPEGM-HPEGM) had been formed and the motion of PEO chains had been improved. The polymer electrolytes possessed excellent thermal stability and electrochemical stability. And when the weight ratio of MPEGM to HPEGM to MPEG7-Al ester was 4:1:5, the maximum ionic conductivity value reached 0.43 × 10-3S/cm with n (Li+): n (EO) =1:20 at 30°C.

AB - A novel comb-like copolymer electrolyte was designed by co-polymerizing of two macro-monomers: methoxy-poly (ethylene glycol) methacrylate (MPEGM) and hexadecal-poly (ethylene glycol) methacrylate (HPEGM), tris (methoxypolyethyleneglycol) aluminate ester (MPEG-Al ester), Li-salt (LiClO4). Performances of the polymer electrolytes were studied by FT-IR, DSC and alternating current (AC) impedance and so on. The results showed that P (MPEGM-HPEGM) had been formed and the motion of PEO chains had been improved. The polymer electrolytes possessed excellent thermal stability and electrochemical stability. And when the weight ratio of MPEGM to HPEGM to MPEG7-Al ester was 4:1:5, the maximum ionic conductivity value reached 0.43 × 10-3S/cm with n (Li+): n (EO) =1:20 at 30°C.

KW - Comb-like copolymer

KW - Ionic conductivity

KW - MPEG-Al ester

KW - Solid polymer electrolyte

UR - http://www.scopus.com/inward/record.url?scp=84890150840&partnerID=8YFLogxK

U2 - 10.3969/j.issn.1001-9731.2013.19.023

DO - 10.3969/j.issn.1001-9731.2013.19.023

M3 - 文章

AN - SCOPUS:84890150840

SN - 1001-9731

VL - 44

SP - 2844

EP - 2848

JO - Gongneng Cailiao/Journal of Functional Materials

JF - Gongneng Cailiao/Journal of Functional Materials

IS - 19

ER -

Study and fabrication of lithium ion batteries using tris (methoxypolyethyleneglycol) aluminate esters as plasticizer for polymer electrolyte

摘要

联合国可持续发展目标

访问文件

其它文件与链接

指纹

引用此