Study on catalytic combustion of benzene over cerium based catalyst supported on cordierite

Qiong Huang; Wen Jiao Ma; Xiao Kang Yan; Ying Wen Chen; She Min Zhu; Shu Bao Shen

Study on catalytic combustion of benzene over cerium based catalyst supported on cordierite

Qiong Huang, Wen Jiao Ma, Xiao Kang Yan, Ying Wen Chen, She Min Zhu, Shu Bao Shen

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A series of MnCeO_x catalysts supported on cordierite honeycomb were prepared by an impregnation method with adding citric acid and using Mn(NO₃)₂ and Ce(NO₃)₂·6H₂O. The effect of the molar ratio of Mn/Ce, calcinations temperature and time, the amount of citric acid on the catalytic properties for the complete oxidation of benzene were investigated. The orthogonal experiment was designed to get the best of technological parameter. These catalysts were characterized by XRD, H₂-TPR and SEM techniques. The results show that the MnCeO_x/Cord catalyst with Mn/Ce molar ratio of 19/21, calcining with 7 h and Mⁿ⁺/(citric acid) molar ratio of 6 exhibits high catalytic performance. When the concentration of benzene was 15×10^-3 and the gaseous hourly space velocity was 20000 h^-1, the conversion of toluene was 99.1% at the reaction temperature of 300°C.

源语言	英语
页（从-至）	3079-3083
页数	5
期刊	Gongneng Cailiao/Journal of Functional Materials
卷	43
期	22
出版状态	已出版 - 30 11月 2012

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title = "Study on catalytic combustion of benzene over cerium based catalyst supported on cordierite",

abstract = "A series of MnCeOx catalysts supported on cordierite honeycomb were prepared by an impregnation method with adding citric acid and using Mn(NO3)2 and Ce(NO3)2·6H2O. The effect of the molar ratio of Mn/Ce, calcinations temperature and time, the amount of citric acid on the catalytic properties for the complete oxidation of benzene were investigated. The orthogonal experiment was designed to get the best of technological parameter. These catalysts were characterized by XRD, H2-TPR and SEM techniques. The results show that the MnCeOx/Cord catalyst with Mn/Ce molar ratio of 19/21, calcining with 7 h and Mn+/(citric acid) molar ratio of 6 exhibits high catalytic performance. When the concentration of benzene was 15×10-3 and the gaseous hourly space velocity was 20000 h-1, the conversion of toluene was 99.1% at the reaction temperature of 300°C.",

keywords = "Benzene, Catalysts, Catalytic combustion, MnCeO",

author = "Qiong Huang and Ma, {Wen Jiao} and Yan, {Xiao Kang} and Chen, {Ying Wen} and Zhu, {She Min} and Shen, {Shu Bao}",

year = "2012",

month = nov,

day = "30",

language = "英语",

volume = "43",

pages = "3079--3083",

journal = "Gongneng Cailiao/Journal of Functional Materials",

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number = "22",

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TY - JOUR

T1 - Study on catalytic combustion of benzene over cerium based catalyst supported on cordierite

AU - Huang, Qiong

AU - Ma, Wen Jiao

AU - Yan, Xiao Kang

AU - Chen, Ying Wen

AU - Zhu, She Min

AU - Shen, Shu Bao

PY - 2012/11/30

Y1 - 2012/11/30

N2 - A series of MnCeOx catalysts supported on cordierite honeycomb were prepared by an impregnation method with adding citric acid and using Mn(NO3)2 and Ce(NO3)2·6H2O. The effect of the molar ratio of Mn/Ce, calcinations temperature and time, the amount of citric acid on the catalytic properties for the complete oxidation of benzene were investigated. The orthogonal experiment was designed to get the best of technological parameter. These catalysts were characterized by XRD, H2-TPR and SEM techniques. The results show that the MnCeOx/Cord catalyst with Mn/Ce molar ratio of 19/21, calcining with 7 h and Mn+/(citric acid) molar ratio of 6 exhibits high catalytic performance. When the concentration of benzene was 15×10-3 and the gaseous hourly space velocity was 20000 h-1, the conversion of toluene was 99.1% at the reaction temperature of 300°C.

AB - A series of MnCeOx catalysts supported on cordierite honeycomb were prepared by an impregnation method with adding citric acid and using Mn(NO3)2 and Ce(NO3)2·6H2O. The effect of the molar ratio of Mn/Ce, calcinations temperature and time, the amount of citric acid on the catalytic properties for the complete oxidation of benzene were investigated. The orthogonal experiment was designed to get the best of technological parameter. These catalysts were characterized by XRD, H2-TPR and SEM techniques. The results show that the MnCeOx/Cord catalyst with Mn/Ce molar ratio of 19/21, calcining with 7 h and Mn+/(citric acid) molar ratio of 6 exhibits high catalytic performance. When the concentration of benzene was 15×10-3 and the gaseous hourly space velocity was 20000 h-1, the conversion of toluene was 99.1% at the reaction temperature of 300°C.

KW - Benzene

KW - Catalysts

KW - Catalytic combustion

KW - MnCeO

UR - http://www.scopus.com/inward/record.url?scp=84871973305&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:84871973305

SN - 1001-9731

VL - 43

SP - 3079

EP - 3083

JO - Gongneng Cailiao/Journal of Functional Materials

JF - Gongneng Cailiao/Journal of Functional Materials

IS - 22

ER -

Study on catalytic combustion of benzene over cerium based catalyst supported on cordierite

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