摘要
The charge/discharge, electrochemical impedance, cyclic voltammogram, and cycling behaviors of crystalline K xMnO 2·nH 2O as cathode material for supercapacitors in Li 2SO 4, Na 2SO 4, and K 2SO 4 electrolytes were compared. The different power and cycling performance of K xMnO 2·nH 2O during charge/discharge in the three electrolytes were elucidated by analyzing its composition and structure evolution. Compared with the Li 2SO 4 and Na 2SO 4 electrolytes, the highest ionic conductivity of K 2SO 4 electrolyte, the fastest charge-transfer process and slightest structural evolution of K xMnO 2·nH 2O during charge/discharge in the K 2SO 4 electrolyte lead to a superior power and cycling behavior for supercapacitor application.
源语言 | 英语 |
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页(从-至) | 56-61 |
页数 | 6 |
期刊 | Journal of Power Sources |
卷 | 223 |
DOI | |
出版状态 | 已出版 - 1 2月 2013 |
已对外发布 | 是 |