Sulfination of Unactivated Allylic Alcohols via Sulfinate-Sulfone Rearrangement

Yan Wang, Guangming Wu, Kaiyu Yan, Jiaheng Qin, Rui Liu, Nannan Rong, Yongming Tang, Teck Peng Loh, Peizhong Xie

科研成果: 期刊稿件文章同行评审

3 引用 (Scopus)

摘要

A dehydrative cross-coupling of unactivated allylic alcohols with sulfinic acids was achieved under catalyst-free conditions. This reaction proceeded via allyl sulfination and concomitant allyl sulfinate-sulfone rearrangement. Various allylic sulfones could be obtained in good to excellent yields with water as the only byproduct. This study expands the synthetic toolbox for constructing allylic sulfone molecules.

源语言英语
页(从-至)8895-8900
页数6
期刊Organic Letters
25
49
DOI
出版状态已出版 - 15 12月 2023
已对外发布

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