TY - JOUR
T1 - Syntheses, crystal structures and spectroscopic properties of the novel complexes [M(MOBPT)*2 (H2O)2](ClO4)2·4H2O (M = CoII and NiII)
AU - Zhu, Dunru
AU - Song, You
AU - Liu, Yongjiang
AU - Xu, Yan
AU - Zhang, Yong
AU - You, Xiaozeng
AU - Raj, S. Shanmuga Sundara
AU - Fun, Hoong Kun
PY - 2000/10
Y1 - 2000/10
N2 - The novel cobalt(II) and nickel(II) complexes with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) have been synthesized and their molecular structures determined by X-ray analysis, i.r. and by ESI-MS spectroscopy. The metal atom is in a distorted octahedral environment. Two bidentate chelating ligands (MOBPT) coordinate to the metal center equatorially and two water molecules coordinate axially. Each MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. Magnetic measurements show that the complexes are high-spin species in the 75-300 K range.
AB - The novel cobalt(II) and nickel(II) complexes with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) have been synthesized and their molecular structures determined by X-ray analysis, i.r. and by ESI-MS spectroscopy. The metal atom is in a distorted octahedral environment. Two bidentate chelating ligands (MOBPT) coordinate to the metal center equatorially and two water molecules coordinate axially. Each MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. Magnetic measurements show that the complexes are high-spin species in the 75-300 K range.
UR - http://www.scopus.com/inward/record.url?scp=0034299632&partnerID=8YFLogxK
U2 - 10.1023/A:1007037326099
DO - 10.1023/A:1007037326099
M3 - 文章
AN - SCOPUS:0034299632
SN - 0340-4285
VL - 25
SP - 589
EP - 593
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 5
ER -