@article{5ad7e2fa049245f69c05e6768cd99612,
title = "Synthesis and characterization of a two-coordinate manganese complex and its reaction with molecular hydrogen at room temperature",
abstract = "The (cAAC)2Mn complex (cAAC=cyclic alkyl(amino)carbene) features a linear two-coordinate Mn-center. The antiferromagnetic coupling of a radical electron, delocalized on two carbene C-atoms, with the central MnI having d6 electronic configuration, mainly contributes to the S T=3/2 ground state. Treatment of (cAAC) 2Mn with H2 at RT resulted in the addition of H-atoms at both {"}carbene{"} C-atoms, leaving the central Mn-atom in the S T=5/2 spin ground state.",
keywords = "coordination modes, cyclic alkyl(amino)carbene, density functional calculations, dihydrogen splitting, manganese",
author = "Samuel, {Prinson P.} and Mondal, {Kartik Chandra} and Roesky, {Herbert W.} and Markus Hermann and Gernot Frenking and Serhiy Demeshko and Franc Meyer and St{\"u}ckl, {A. Claudia} and Christian, {Jonathan H.} and Dalal, {Naresh S.} and Liviu Ungur and Chibotaru, {Liviu F.} and Kevin Pr{\"o}pper and Alke Meents and Birger Dittrich",
year = "2013",
month = nov,
day = "4",
doi = "10.1002/anie.201304642",
language = "英语",
volume = "52",
pages = "11817--11821",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "45",
}