Synthesis and crystal structure of (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide

Zheng Fang; Ke Tao Chen; Xiao Lin Li; Wen Bo Zeng; Kai Guo

doi:10.14102/j.cnki.0254-5861.2011-0436

Synthesis and crystal structure of (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide

Zheng Fang, Ke Tao Chen, Xiao Lin Li, Wen Bo Zeng, Kai Guo

生物与制药工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The title compound (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide (C₁₉H₂₀N₂O₂, M_r = 308.37) was synthesized by the reaction of (S)-α-amino-Σ-caprolactam with 4-phenyl-benzoyl chloride. Its chemical structure was determined by ¹H NMR, ¹³C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the triclinic system, space group P1¯ with a = 8.2650(17), b = 13.774(3), c = 15.109(3) Å, β = 90.20(3)°, V = 1645.6(6) Å³, Z = 4, D_c = 1.245 g/cm³, μ = 0.081 mm^-1, F(000) = 656, R = 0.0756 and wR = 0.1491 for 5964 observed reflections with I > 2σ(I). The title compound was also used to prepare polyamide.

源语言	英语
页（从-至）	82-86
页数	5
期刊	Jiegou Huaxue
卷	34
期	1
DOI	https://doi.org/10.14102/j.cnki.0254-5861.2011-0436
出版状态	已出版 - 15 1月 2015

访问文件

10.14102/j.cnki.0254-5861.2011-0436

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{6eb3cb0a1bf34178897388ebb232aef0,

title = "Synthesis and crystal structure of (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide",

abstract = "The title compound (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide (C19H20N2O2, Mr = 308.37) was synthesized by the reaction of (S)-α-amino-Σ-caprolactam with 4-phenyl-benzoyl chloride. Its chemical structure was determined by 1H NMR, 13C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the triclinic system, space group P1¯ with a = 8.2650(17), b = 13.774(3), c = 15.109(3) {\AA}, β = 90.20(3)°, V = 1645.6(6) {\AA}3, Z = 4, Dc = 1.245 g/cm3, μ = 0.081 mm-1, F(000) = 656, R = 0.0756 and wR = 0.1491 for 5964 observed reflections with I > 2σ(I). The title compound was also used to prepare polyamide.",

keywords = "Caprolactam, Crystal structure, Lysine, Polyamide",

author = "Zheng Fang and Chen, {Ke Tao} and Li, {Xiao Lin} and Zeng, {Wen Bo} and Kai Guo",

note = "Publisher Copyright: {\textcopyright} 2015 Chinese J. Struct. Chem.",

year = "2015",

month = jan,

day = "15",

doi = "10.14102/j.cnki.0254-5861.2011-0436",

language = "英语",

volume = "34",

pages = "82--86",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "1",

}

TY - JOUR

T1 - Synthesis and crystal structure of (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide

AU - Fang, Zheng

AU - Chen, Ke Tao

AU - Li, Xiao Lin

AU - Zeng, Wen Bo

AU - Guo, Kai

PY - 2015/1/15

Y1 - 2015/1/15

N2 - The title compound (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide (C19H20N2O2, Mr = 308.37) was synthesized by the reaction of (S)-α-amino-Σ-caprolactam with 4-phenyl-benzoyl chloride. Its chemical structure was determined by 1H NMR, 13C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the triclinic system, space group P1¯ with a = 8.2650(17), b = 13.774(3), c = 15.109(3) Å, β = 90.20(3)°, V = 1645.6(6) Å3, Z = 4, Dc = 1.245 g/cm3, μ = 0.081 mm-1, F(000) = 656, R = 0.0756 and wR = 0.1491 for 5964 observed reflections with I > 2σ(I). The title compound was also used to prepare polyamide.

AB - The title compound (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide (C19H20N2O2, Mr = 308.37) was synthesized by the reaction of (S)-α-amino-Σ-caprolactam with 4-phenyl-benzoyl chloride. Its chemical structure was determined by 1H NMR, 13C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the triclinic system, space group P1¯ with a = 8.2650(17), b = 13.774(3), c = 15.109(3) Å, β = 90.20(3)°, V = 1645.6(6) Å3, Z = 4, Dc = 1.245 g/cm3, μ = 0.081 mm-1, F(000) = 656, R = 0.0756 and wR = 0.1491 for 5964 observed reflections with I > 2σ(I). The title compound was also used to prepare polyamide.

KW - Caprolactam

KW - Crystal structure

KW - Lysine

KW - Polyamide

UR - http://www.scopus.com/inward/record.url?scp=84920911400&partnerID=8YFLogxK

U2 - 10.14102/j.cnki.0254-5861.2011-0436

DO - 10.14102/j.cnki.0254-5861.2011-0436

M3 - 文章

AN - SCOPUS:84920911400

SN - 0254-5861

VL - 34

SP - 82

EP - 86

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 1

ER -

Synthesis and crystal structure of (S)-N-(2-oxoazepan-3-yl)biphenyl-4-carboxamide

摘要

访问文件

其它文件与链接

指纹

引用此