Synthesis and ligand properties of a persistent, all-carbon fourmembered-ring allene

Mohand Melaimi, Pattiyil Parameswaran, Bruno Donnadieu, Gernot Frenking, Guy Bertrand

科研成果: 期刊稿件文章同行评审

105 引用 (Scopus)

摘要

A single donor substituent at each terminus is sufficient to make the CCC skeleton of allenes very flexible and give carbon(0) character to the central carbon atom. This allows the synthesis of a four-membered carbocyclic allene, which can be doubly protonated and behaves as a very strong η1- donor ligand for transition metals (see scheme).

源语言英语
页(从-至)4792-4795
页数4
期刊Angewandte Chemie - International Edition
48
26
DOI
出版状态已出版 - 15 6月 2009
已对外发布

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