TY - JOUR
T1 - Synthesis, Characterization and Thermal Properties of Bio-Based Poly(Ethylene 2,5-Furan Dicarboxylate)
AU - Yu, Zuolong
AU - Zhou, Jiadong
AU - Cao, Fei
AU - Zhang, Qiguo
AU - Huang, Kaixuan
AU - Wei, Ping
N1 - Publisher Copyright:
© 2016 Taylor & Francis Group, LLC.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - Poly(ethylene 2,5-furan dicarboxylate) (PEF), based on renewable resources, was synthesized using several different polycondensation methods and then characterized. In this study the properties of polycondensed PEF were compared using five types of catalysts and two types of monomers. For the optimal catalyst, the influence of the amount of catalyst, polycondensation temperature and polycondensation time were investigated and, thereafter, direct and indirect polycondensations were compared at the optimum conditions. Various properties of PEF were characterized by Fourier transform infrared spectroscopy, intrinsic viscosity, gel permeation chromatography, 1H NMR, differential scanning calorimetry, dynamic mechanical thermal analysis, thermogravimetric analysis, and X-ray diffraction for comparison with the properties of polyethylene terephthalate PET. In addition, the rheological behaviour and mechanical properties of the PEFs were tested. The results confirmed that the obtained properties of PEF were similar to the corresponding properties of PET.
AB - Poly(ethylene 2,5-furan dicarboxylate) (PEF), based on renewable resources, was synthesized using several different polycondensation methods and then characterized. In this study the properties of polycondensed PEF were compared using five types of catalysts and two types of monomers. For the optimal catalyst, the influence of the amount of catalyst, polycondensation temperature and polycondensation time were investigated and, thereafter, direct and indirect polycondensations were compared at the optimum conditions. Various properties of PEF were characterized by Fourier transform infrared spectroscopy, intrinsic viscosity, gel permeation chromatography, 1H NMR, differential scanning calorimetry, dynamic mechanical thermal analysis, thermogravimetric analysis, and X-ray diffraction for comparison with the properties of polyethylene terephthalate PET. In addition, the rheological behaviour and mechanical properties of the PEFs were tested. The results confirmed that the obtained properties of PEF were similar to the corresponding properties of PET.
KW - 2,5-Furan dicarboxylic acid
KW - characterization
KW - mechanical properties
KW - poly(ethylene 2,5-furan dicarboxylate)
UR - http://www.scopus.com/inward/record.url?scp=85001875423&partnerID=8YFLogxK
U2 - 10.1080/00222348.2016.1238335
DO - 10.1080/00222348.2016.1238335
M3 - 文章
AN - SCOPUS:85001875423
SN - 0022-2348
VL - 55
SP - 1135
EP - 1145
JO - Journal of Macromolecular Science - Physics
JF - Journal of Macromolecular Science - Physics
IS - 12
ER -
